132216-59-2Relevant academic research and scientific papers
Cyclisation d'allylsilanes: approche biomimetique du squelette cyclogeranyle
Serramedan, D.,Delmond, B.,Deleris, G.,Dunogues, J.,Pereyre, M.,Filliatre, C.
, p. 79 - 84 (1990)
Allylsilanes were obtained by 1,4-disilylation of myrcene and epoxymyrcene.Upon treatment with a Lewis acid the epoxy allylsilane 5 was cyclized to give the hydroxylated homoallylsilane 8 with a cyclogeranyl skeleton.
