Cyclisation d'allylsilanes: approche biomimetique du squelette cyclogeranyle

DOI: 10.1016/0022-328X(90)87005-X

Source and publish data:

Journal of Organometallic Chemistry p. 79 - 84 (1990)

Update date:2022-08-02

Topics:

Authors:

Serramedan, D.

Delmond, B.

Deleris, G.

Dunogues, J.

Pereyre, M.

Filliatre, C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(90)87005-X

Allylsilanes were obtained by 1,4-disilylation of myrcene and epoxymyrcene.Upon treatment with a Lewis acid the epoxy allylsilane 5 was cyclized to give the hydroxylated homoallylsilane 8 with a cyclogeranyl skeleton.

Full text of DOI:10.1016/0022-328X(90)87005-X

Products guided by the article

Product name:2,2-Dimethyl-4-methylene-3-trimethylsilanylmethyl-cyclohexanol

Cas No:132216-59-2

R&D Labs maybe for 132216-59-2

Zhaodu Fine Chemical Plant

Contact:86-310-8067016

Address:East Fuhua Road,Tiexi Chemical Industrial Estate,Hebei,China
Hangzhou Yanshan Chemical Co.,Ltd.

Contact:86-571- 87698076

Address:Room 1001, #1 Building, Zhongtian MCC, No.2 Youzhinong, Wenyi West Road, Xihu District, Hangzhou, China
Jiangsu Hualun Chemical Industry Co., Ltd

website:http://www.hualunchem.com

Contact:+86-0514-86464168 86507985

Address:39# Middle Renmin Road, Dinghuo Town
Shanghai TBBMed Co.,Ltd

website:http://www.tbbmed.com

Contact:86--21-50498136

Address:Room 6002, Building 7-1, No.160 Basheng Road,Pudong Area,Shanghai China
Evergreen Chemical Industry Ltd.

Contact:86-553-4918210

Address:6#2-602 Wanhaobailing

Relevant to this article

A novel rearrangement of cyclic glutamine derivatives: Ring contraction in 3,6-diamino-2,3,4,5-tetrahydropyridin-2-ones to yield 5-iminoproline amides

Doi:10.1002/ejoc.201100404
(2011)
on Water C(sp³)-H Functionalization/C-O/C-N Bonds Formations: Synthesis of Functionalized Oxazolidines and Imidazolidines

Doi:10.1021/acs.joc.6b01850
(2016)
NEW DITERPENOIDS FROM PACHYDICTYON CORIACEUM

Doi:10.1246/cl.1982.1517
(1982)
Modular Total Syntheses of Hyperforin, Papuaforins A, B, and C via Gold(I)-Catalyzed Carbocyclization

Doi:10.1021/acs.joc.8b00426
(2018)
Synthesis, structure, dynamics, and selective methylation of platinum and palladium diphosphametallacyclobutane complexes

Doi:10.1021/om3005367
(2012)
The Dithiole Series. Part 8. Synthesis of Ring-fused 1,2-Dithiolylium and Isothiazolium Salts from Complexes containing Cyclopalladated Ligands

Doi:10.1039/P19900002881
(1990)

Article Doi