13224-05-0Relevant academic research and scientific papers
Diversity oriented synthesis of conjugate dienes and alkenylcyclopropanes utilizing silyl group-substituted titanium carbene complexes as bimetallic synthetic reagents
Takeda, Takeshi,Mori, Ayako,Fujii, Tomoya,Tsubouchi, Akira
, p. 5776 - 5786 (2014)
Diversity oriented synthesis of conjugate dienes and alkenylcyclopropanes by the sequential reactions using silyl group-substituted titanium carbene complexes was studied. Dienylsilanes were obtained by the olefination of carbonyl compounds with γ-silylvi
Preparation of allylsilanes by the olefination of carbonyl compounds using β-silylthioacetals
Takeda, Takeshi,Watanabe, Mikako,Rahim, Abdur,Fujiwara, Tooru
, p. 3753 - 3756 (2007/10/03)
Titanocene(II)-promoted olefination of various carbonyl compounds using 1,1-bis(phenylthio)-2-triorganosilylethanes gave allylsilanes in good yields. γ-Alkoxy and alkylthio group substituted allylsilanes were also obtained by using carboxylic esters and thiolesters, respectively.
