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Upstream product

• 78317-79-0 2-(4-fluorophenyl)-1,2,3,4-tetrahydroisoquinoline 
• 762-04-9 phosphonic acid diethyl ester 

Relevant academic research and scientific papers

Cross-dehydrogenative coupling reaction using copper oxide impregnated on magnetite in deep eutectic solvents

The synthesis of different tetrahydroisoquinolines using choline chlorideethylene glycol as a deep eutectic solvent (DES) and copper(ii) oxide impregnated on magnetite as a catalyst has been accomplished successfully. The copper catalyst amount is the low

Oxidation of the inert sp3C-H bonds of tetrahydroisoquinolines through C-H activation relay (CHAR): construction of functionalized isoquinolin-1-ones

A TBN/O2-initiated oxidation of the relatively inert 3,4-C-H bonds of THIQs was accomplished, in which the existence of an α-phosphoric ester group is crucial to enable dioxygen trapping and intramolecular HAT (C-H activation relay,CHAR), reali

A Porous and Stable Porphyrin Metal-Organic Framework as an Efficient Catalyst towards Visible-Light-Mediated Aerobic Cross-Dehydrogenative-Coupling Reactions

Porphyrin metal-organic frameworks (PMOFs) are emerging as heterogeneous photocatalysts owing to the well-designed frameworks incorporated with powerful light-harvesting porphyrin chromophores. The porous and stable framework Ir?PCN-224 (which is also den

Electrochemical Cross-Dehydrogenative Coupling of N-Aryl-tetrahydroisoquinolines with Phosphites and Indole

A metal- and reagent-free, electrochemical cross-dehydrogenative coupling reaction of N-aryl-tetrahydroisoquinolines with phosphites and indole is developed. This method provides an environmentally benign and simple approach for the construction of C–P an

Thiourea-Catalyzed Cross-Dehydrogenative Coupling of C(sp3)–H with Diethyl Phosphite

The efficient thiourea-catalyzed cross-dehydrogenative coupling of C(sp3)–H with diethyl phosphite by using tert-butyl peroxide as a terminal oxidant was explored. This protocol further expands the application scope of H-bond donors and also pr

The singlet excited state of BODIPY promoted aerobic cross-dehydrogenative-coupling reactions under visible light

In contrast to previous studies, we disclose for the first time that the singlet excited state (1PS?) of BODIPY rather than the triplet excited state (3PS?) can drive C-H bond activation to form C-C and C-P bonds smoothly, which offers new methods to promote organic transformation under visible light irradiation.

Light-mediated heterogeneous cross dehydrogenative coupling reactions: Metal oxides as efficient, recyclable, photoredox catalysts in C-C bond-forming reactions

Let there be light: A heterogeneous photocatalytic system based on easily recyclable TiO2 or ZnO allows cross dehydrogenative coupling reactions of tertiary amines. The newly developed protocols have successfully been applied to various C-C and

A scalable, efficient gold-catalyzed oxidative phosphonation of sp 3 C-H bonds using air as sustainable oxidant

A scalable, efficient gold-catalyzed oxidative phosphonation of sp 3 C-H bonds with various diarylphosphine oxides and dialkyl phosphites has been developed by using air as a sustainable oxidant under mild reaction conditions. It provides an ea

Photoredox catalyzed C-P bond forming reactions - Visible light mediated oxidative phosphonylations of amines

A visible light mediated, carbon-phosphorus bond forming reaction has been developed. With the use of a readily available photoredox catalyst, α-amino phosphonates were obtained in good yields under mild reaction conditions. The Royal Society of Chemistry