132273-93-9

Basic information

• Product Name: (1R,1'R)-N-(2'-hydroxy-1'-phenylethyl)-N-methyl-1-phenylethylamine
• Synonyms: (1R,1'R)-N-(2'-hydroxy-1'-phenylethyl)-N-methyl-1-phenylethylamine
• CAS NO: 132273-93-9
• Molecular Weight: 255.36
• Mol File: 132273-93-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1R,1'R)-N-(2'-hydroxy-1'-phenylethyl)-N-methyl-1-phenylethylamine(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,1'R)-N-(2'-hydroxy-1'-phenylethyl)-N-methyl-1-phenylethylamine(132273-93-9)
• EPA Substance Registry System: (1R,1'R)-N-(2'-hydroxy-1'-phenylethyl)-N-methyl-1-phenylethylamine(132273-93-9)

Safety Data

• Hazardous Substances Data: 132273-93-9(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 84773-28-4 (R)-2-(methylamino)-2-phenylethanol 
• 56613-80-0 D-2-phenylglycinol 
• 132273-87-1 (2R,4R)-2,N-dimethyl-4-phenyl-1,3-oxazolidine 
• 100-58-3 phenylmagnesium bromide 
• 131320-25-7 N-[(R)-2'-hydroxy-1'-phenylethyl]-(R)-1-phenyl-1-ethylamine 
• 74-88-4 methyl iodide 
• 917-54-4 methyllithium 
• 153924-63-1 β-[(phenylmethylene)amino]-[R-(E)-]-benzeneethanol 

Relevant articles and documents

Diastereoselective addition of chiral aliphatic imines and 2-alkyl-1,3-oxazolidines to organometallic reagents

The reaction of organocerium reagents with chiral aliphatic imines derived from (R)-O-methylphenylglycinol afforded the corresponding amines with high diastereoselectivity. In contrast, the reaction of Grignard reagents with chiral 2-alkyl-1,3-oxazolidines derived from (R)-N-methylphenylglycinol afforded the amines with changeover in diastereoselectivity.

The absolute configuration and stereoselective Grignard reaction of N-substituted 4-phenyl-1,3-oxazolidines

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