13235-87-5Relevant academic research and scientific papers
SYNTHESE DE POLYSILOXANES FLUORES PARTIE I. HYDROSILYLATION D'OLEFINES FLUOREES ALLYLIQUES ET STRYRENIQUES
Boutevin, B.,Pietrasanta, Y.,Youssef, B.
, p. 57 - 74 (1986)
New fluorinated silanes may be prepared by reaction of mono- or dichloromethylsilane with either pentafluorostyrene or fluorinated allyl ethers.The hydrosilylation reaction is carried out in the presence of H2PtCl6.The products are identified unambiguousl
THE REACTIONS OF HYDROSILANES WITH TRIFLUOROPROPENE AND PENTAFLUOROSTYRENE CATALYZED BY RUTHENIUM, RHODIUM AND PALLADIUM COMPLEXES
Ojima, Iwao,Fuchikami, Takamasa,Yatabe, Momoko
, p. 335 - 346 (1984)
The reactions of hydrosilanes with trifluoropropene (TFP) and pentafluorostyrene (PFS) catalyzed by Ru3(CO)12 or RhCl(PPh3)3 give β-Rf-vinylsilane (1) and/or β-Rf-ethylsilane (2) (Rf=perfluorocarbon group).The 1/2 ratio is highly dependent on the nature of hydrosilane used.The ruthenium catalyst favors the formation of 1 compared with the rhodium catalyst.Neither α-Rf-vinylsilane nor α-Rf-ethylsilane was formed at all.Possible mechanisms which can accommodate characteristic features of these reactions are discussed.The hydrosilylation of TFP with dichloromethylsilane catalyzed by PdCl2(PhCN)2/2PPh3 gives the α-adduct (9a) exclusively, and this is transformed to the corresponding dialkoxysilanes, silane diol, oligosilane diols and cyclic oligosiloxanes.
