132353-02-7

Basic information

• Product Name: 2-(tetrahydrofuran-2'-yl)-1-phenylsulphonyl-1-(pyridine-2-thiyl)ethane
• CAS NO: 132353-02-7
• Molecular Weight: 349.475
• Mol File: 132353-02-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(tetrahydrofuran-2'-yl)-1-phenylsulphonyl-1-(pyridine-2-thiyl)ethane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(tetrahydrofuran-2'-yl)-1-phenylsulphonyl-1-(pyridine-2-thiyl)ethane(132353-02-7)
• EPA Substance Registry System: 2-(tetrahydrofuran-2'-yl)-1-phenylsulphonyl-1-(pyridine-2-thiyl)ethane(132353-02-7)

Safety Data

• Hazardous Substances Data: 132353-02-7(Hazardous Substances Data)

Upstream product

• 5535-48-8 PVS 
• 136409-48-8 Tetrahydro-furan-2-carboxylic acid 2-thioxo-2H-pyridin-1-yl ester 
• 109-99-9 tetrahydrofuran 

Relevant articles and documents

Synthesis of C-Nucleosides via Radical Coupling Reaction

Photolysis of O-acyl derivatives of N-hydroxy-2-thiopyridone, prepared from tetrahydrofuran-2-carboxylic acid, D-ribofuranosylmethanoic acid, and D-ribopyranosylmethanoic acid, gave the corresponding C-nucleoside derivatives in the presence of heteroaromatic compounds via radical pathways.The essential step in this method is a radical coupling reaction of D-ribofuranosyl radical or D-ribopyranosyl radical and some heteroaromatic bases.This is a new method for the preparation of C-nucleosides using sugar carboxylic acids.

N-HYDROXY-2-PYRIDINETHIONE: A MILD AND CONVENIENT SOURCE OF HYDROXYL RADICALS

N-Hydroxy-2-thiopyridone gives hydroxyl radicals on irradiationm with visible light and these can be incorporated in useful radical chain processes involving hydrogen abstraction.