132356-16-2Relevant academic research and scientific papers
Chloroallyl Anion: Highly Regio- and Diastereoselective α-Addition of Chloroallyl Zinc Reagent to Carbonyl Compounds
Mallaiah, K.,Satyanarayana, J.,Ila, H.,Junjappa, H.
, p. 3145 - 3148 (1993)
The chloroallyl zinc reagent generated insitu by deprotonation of allyl chloride in the presence of lithium diisopropylamide and zinc chloride undergoes highly regio- and diastereoselective α-addition to carbonyl compounds to give syn chlorohydrins which
A One-Pot Reaction toward the Diastereoselective Synthesis of Substituted Morpholines
Aubineau, Thomas,Cossy, Janine
supporting information, p. 7419 - 7423 (2018/12/11)
The diastereoselective synthesis of various substituted morpholines has been achieved from vinyloxiranes and amino-alcohols under sequential Pd(0)-catalyzed Tsuji-Trost/Fe(III)-catalyzed heterocyclization. Using the same strategy, 2,6-, 2,5-, and 2,3-disubstituted as well as 2,5,6- and 2,3,5-trisubstituted morpholines were obtained in good to excellent yields and diastereoselectivities.
A Facile Synthesis of α,β-Unsaturated Epoxides via Allyldi-isobutyltelluronium Bromide
Zhou, Zhang-Lin,Sun, You-Shou,Shi, Li-Lan,Huang, Yao-Zeng
, p. 1439 - 1440 (2007/10/02)
In the presence of solid KOH, allyldi-isobutyltelluronium bromide 2 reacts directly with aromatic aldehydes at room temperature under solid-liquid phase-transfer conditions to afford α,β-unsaturated epoxides 3 in excellent yields.
