132360-46-4

Upstream product

• 130525-72-3 ethyl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 16697-49-7 3,4,6-tri-O-benzyl-1,2-O-(methoxyethylidene)-β-D-mannopyranose 
• 129214-38-6 2-O-acetyl-3,4,6-tri-O-benzyl-D-mannopyranoside 
• 98-88-4 benzoyl chloride 
• 75-08-1 ethanethiol 
• 129750-23-8 Ethyl 3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 

Downstream Products

• 132360-50-0 3,4,5-tri-O-benzyl-1,2-O-cyclohexylidene-6-O-(2',3',4',6'-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol 
• 132360-50-0 3,4,5-tri-O-benzyl-1,2-O-cyclohexylidene-6-O-(2',3',4',6'-tetra-O-benzyl-α-D-mannopyranosyl)-L-myo-inositol 
• 132437-47-9 3,4,5-tri-O-benzyl-1,2-O-cyclohexylidene-6-O-(3',4',6'-tri-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol 
• 132360-49-7 3,4,5-tri-O-benzyl-1,2-O-cyclohexylidene-6-O-(3',4',6'-tri-O-benzyl-α-D-mannopyranosyl)-L-myo-inositol 
• 866322-01-2 ethyl 2-O-benzoyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-1-α-D-thiomannopyranoside 
• 125608-47-1 Benzoic acid (2R,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-bromo-tetrahydro-pyran-3-yl ester 
• 170452-77-4 3,4,5,6-tetra-O-benzyl-2-O-(2'-O-benzoyl-3',4',6'-tri-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol 
• 493008-73-4 methyl 2,4-di-O-benzyl-3,6-di-O-(2-O-benzoyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-α-D-mannopyranoside 

Relevant academic research and scientific papers

Synthesis of oligosaccharide fragments of mannan from Candida albicans cell wall and their BSA conjugates

3-Aminopropyl glycosides of α-D-mannopyranosyl-(1→2)-α-D- mannopyranosyl-(1→2)-α-D-mannopyranosyl-(1→2) -α-D-mannopyranose, α-D-mannopyranosyl-(1→3)-α-D- mannopyranosyl-(1→2)-α-D-mannopyranosyl-(1→2) -α-D-mannopyranose, and α-D-mannopyranosyl-(1→2)-[α-D- mannopyranosyl-(1→3)]-α-D-mannopyranosyl-(1→2) -α-D-mannopyranosyl-(1→2)-α-D-mannopyranose were efficiently synthesized starting from ethyl 2-O-acetyl(benzoyl)-3,4,6-tri-O-benzyl-1-thio- α-D-mannopyranoside, ethyl 4,6-di-O-benzyl-2-O-benzoyl-1-thio-α-D- mannopyranoside, ethyl 4,6-di-O-benzyl-2,3-di-O-benzoyl-1-thio-α-D- mannopyranoside, and 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl bromide. The oligosaccharide chains synthesized correspond to the three structural types of side chains of mannan from Candida albicans cell wall. A conjugate of the third pentasaccharide with bovine serum albumin was prepared using the squarate method.

Glycosylation using a one-electron-transfer, homogeneous reagent. Application to an efficient synthesis of the trimannosyl core of N-glycosylproteins

Double glycosylation of methyl 2,4-di-O-benzyl-β-D-mannopyranoside with ethyl 2-O-benzoyl-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside using as promoter tris(4-bromophenyl)ammoniumyl hexachloroantimonate, a stable, commercial, and crystalline radical cat