Cas 132369-48-3,3-O-benzyl-4,5-dideoxy-1,2-O-isopropylidene-α-L-glycero-hex-4-en-2-ulopyranose

132369-48-3

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Basic information

Product Name: 3-O-benzyl-4,5-dideoxy-1,2-O-isopropylidene-α-L-glycero-hex-4-en-2-ulopyranose
Synonyms: 3-O-benzyl-4,5-dideoxy-1,2-O-isopropylidene-α-L-glycero-hex-4-en-2-ulopyranose
CAS NO:132369-48-3
Molecular Formula:
Molecular Weight: 276.332
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: 3-O-benzyl-4,5-dideoxy-1,2-O-isopropylidene-α-L-glycero-hex-4-en-2-ulopyranose(CAS DataBase Reference)
NIST Chemistry Reference: 3-O-benzyl-4,5-dideoxy-1,2-O-isopropylidene-α-L-glycero-hex-4-en-2-ulopyranose(132369-48-3)
EPA Substance Registry System: 3-O-benzyl-4,5-dideoxy-1,2-O-isopropylidene-α-L-glycero-hex-4-en-2-ulopyranose(132369-48-3)

Safety Data

Hazard Codes: N/A
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Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 132369-48-3(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 132369-48-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,2,3,6 and 9 respectively; the second part has 2 digits, 4 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 132369-48:
(8*1)+(7*3)+(6*2)+(5*3)+(4*6)+(3*9)+(2*4)+(1*8)=123
123 % 10 = 3
So 132369-48-3 is a valid CAS Registry Number.

132369-48-3Upstream product

132369-48-3Downstream Products

132369-48-3Relevant academic research and scientific papers

Controlled Garegg conditions for selective iodination on pyranose templates

Simao, Ana-Catarina,Silva, Sandrina,Rauter, Amelia P.,Rollin, Patrick,Tatibouet, Arnaud

scheme or table, p. 2286 - 2292 (2011/06/22)

Regio- and stereoselective iodinations under controlled Garegg conditions were performed on vicinal diols and contiguous triols located on pyranose templates. β-D-Fructo- orpsicopyranose-based diols were selectively iodinated at C-5 or C-4, respectively,

Selective iodination of vicinal cis-diols on ketopyranose templates

Simao, Ana Catarina,Tatibou?t, Arnaud,Rauter, Amelia P.,Rollin, Patrick

scheme or table, p. 4602 - 4604 (2010/09/10)

A regio- and stereoselective iodination has been performed on vicinal diols located on ketopyranose templates using the controlled- Garegg conditions. 3-O-Benzyl-1,2-O-isopropylidene-β-d-fructo- or psicopyranoses (1 or 4) were selectively iodinated, respectively, at C-5 or C-4 of the ketoses to afford the l-sorbo or d-sorbo iodohydrins.

Structural probing of ketone catalysts for asymmetric epoxidation

Tu, Yong,Wang, Zhi-Xian,Frohn, Michael,He, Mingqi,Yu, Hongwu,Tang, Yong,Shi, Yian

, p. 8475 - 8485 (2007/10/03)

A series of chiral ketones derived from carbohydrates were investigated as catalysts for the asymmetric epoxidation. Fructose-derived ketones are found to be efficient catalysts. The studies show that the structural requirements for the ketone catalysts are very stringent and different types of olefins may require ketones with different structural arrangements. The current study allows us to further understand the chiral ketone catalyzed asymmetric epoxidation and provides some insight for the development of new catalysts.

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