70551-32-5

Upstream product

• 100-39-0 benzyl bromide 
• 1125824-35-2 C₂₃H₂₆O₆ 
• 6347-01-9 fructopyranose 
• 25018-67-1 1,2;4,5-di-O-isopropylidene-β-D-(-)-fructopyranose 
• 85458-76-0 3-O-Benzyl-1,2:4,5-di-O-isopropylidene-β-D-fructopyranose 

Downstream Products

• 167482-39-5 3-O-Benzyl-1,2-O-isopropylidene-4,5-O-<(1'R)-trans-3'-phenyl-2'-propen-1'-yl>-β-D-fructopyranose 
• 167612-51-3 3-O-Benzyl-1,2-O-isopropylidene-4,5-O-<(1'S)-trans-3'-phenyl-2'-propen-1'-yl>-β-D-fructopyranose 
• 132369-48-3 3-O-benzyl-4,5-dideoxy-1,2-O-isopropylidene-α-L-glycero-hex-4-en-2-ulopyranose 
• 340969-76-8 3,4-di-O-benzyl-1,2-O-isopropylidene-β-D-fructopyranose 
• 927809-64-1 4-O-benzoyl-3-O-benzyl-1,2-O-isopropylidene-β-D-fructopyranose 
• 1106973-90-3 C₃₀H₃₃O₇P 
• 1268598-83-9 C₃₅H₃₈O₁₀ 
• 1268598-81-7 3-O-benzyl-4,5-O-(o-xylylene)-α-D-fructopyranose 3'-O-benzyl-4',5'-O-(o-xylylene)-β-D-fructopyranose 1,2':2,1'-dianhydride 
• 1268598-84-0 3,3'-di-O-benzyl-4:5,4',5'-di-O-(o-xylylene)-di-β-D-fructopyranose 1,2':2,1'-dianhydride 
• 1268598-80-6 3-O-benzyl-1,2-O-isopropylidene-4,5-O-(o-xylylene)-β-D-fructopyranose 
• 1245436-35-4 3-O-benzyl-5-deoxy-5-iodo-1,2-O-isopropylidene-α-L-sorbopyranose 
• 141564-96-7 (2S,3R,4R,5R)-4-Benzyloxy-2-fluoro-hexane-1,3,5-triol 
• 141564-96-7 (2S,3R,4R,5S)-4-Benzyloxy-2-fluoro-hexane-1,3,5-triol 
• 141564-90-1 3-O-benzyl-4-O-tert-butyldimethylsilyl-5-deoxy-5-fluoro-1,2-O-isopropylidene-α-L-sorbopyranose 

Relevant academic research and scientific papers

Synthesis of a poly-hydroxypyrolidine-based inhibitor of Mycobacterium tuberculosis GlgE

(Chemical Equation Presented). Long treatment times, poor drug compliance, and natural selection during treatment of Mycobacterium tuberculosis (Mtb) have given rise to extensively drug-resistant tuberculosis (XDR-TB). As a result, there is a need to iden

Truly catalytic and chemoselective cleavage of benzylidene acetal with phosphomolybdic acid supported on silica gel

Phosphomolybdic acid supported on silica gel provides a truly catalytic method for the chemoselective cleavage of benzylidene acetals having sensitive functional groups under mild conditions. It is easy to perform on large scale owing to minimal catalyst loading (0.5 mol-%). Several sensitive functional groups such as TBDPS ether, -OMs, -OAc, allyl ether, N-Boc, N-Fmoc and N-Cbz are stable under the reaction conditions. In addition, benzylidene acetal is selectively cleaved in the presence of isopropylidene ketal. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.

Aromatic or chiral heterocycle - Balance between 1,3-oxazoline-2-thione and 1,3-oxazolidine-2-thione

1,3-Oxazoline-2-thiones (OXT) and bis-1,3-oxazol-idine-2-thiones (bis-OZT) were selectively prepared depending on the conditions and starting materials used, and then underwent some N- and S-selective reactions. Georg Thieme Verlag Stuttgart.

Asymmetric Cyclopropanation Using New Chiral Auxiliaries Derived from D-Fructose

Acetals of α,β-unsaturated aldehydes with 3-O-alkylated derivatives of 1,2-O-isopropylidene-β-D-fructopyranose and 1,2-O-isopropylidene-β-D-psicopyranose, which are readily available from D-fructose, were cyclopropanated with Et2Zn and CH2I2 with good diastereoselectivity.The effects of structure of the acetals on enantioselectivity were examined.

A Synthesis of 2,6-Dideoxy-2-fluoro-L-glycopyranose from D-Fructose: Synthesis of 1,3,4-Tri-O-acetyl-2,6-dideoxy-2-fluoro-L-talopyranose

2,6-Dideoxy-2-fluoro-α-L-talopyranose has been prepared as its triacetate from inexpensive D-fructose by head-to-tail inversion.