132371-60-9Relevant academic research and scientific papers
Redox Activity, Ligand Protonation, and Variable Coordination Modes of Diimino-Pyrrole Complexes of Palladium
McNeece, Andrew J.,Chang, Mu-Chieh,Filatov, Alexander S.,Anderson, John S.
, p. 7044 - 7050 (2018)
Ligand-based functionality is a prominent method of increasing the reactivity or stability of metal centers in coordination chemistry. Some of the most successful catalysts use ligand-based redox activity, pendant protons, or hemilability in order to spec
Thiophene-fused dithiaoctaphyrins: π-system switching between cross-conjugated and macrocyclic π-networks
Higashino, Tomohiro,Kumagai, Atsushi,Imahori, Hiroshi
, p. 5091 - 5094 (2017/07/12)
We synthesized for the first time octaphyrins with a dithieno[3,4-b:3′,4′-d]thiophene core as thiophene-fused dithiaoctaphyrins with a cross-conjugated structure. The octaphyrins revealed cross-conjugated and macrocyclic 36π-electron networks.
Stepwise syntheses of core-modified, meso-substituted porphyrins
Heo, Phil-Yeon,Shin, Koo,Lee, Chang-Hee
, p. 197 - 200 (2007/10/02)
Simple conditions are discovered to afford modified tripyrrin derivatives by condensation of 2,5-bis(α-hydroxymethyl)pyrrole, thiophene and furan derivatives with pyrrole in the presence of acid catalyst. The core-modified porphyrins were synthesized by acid catalyzed 3+1 condensation of modified tripyrrins with 2,5-bis(α-hydroxymethyl)-substituted pyrrole, thiophene or furan. This new process gives a single porphyrin isomer and overcomes the synthetic problems associated with separation and purification of regioisomeric mixtures.
General Methods for Synthesizing 2,4-Diacylpyrroles and their Precursors Containing One or Two Masked Acyl Groups
Cadamuro, Silvano,Degani, Iacopo,Dughera, Stefano,Fochi, Rita,Gatti, Antonella,Piscopo, Laura
, p. 273 - 284 (2007/10/02)
A thorough study of the synthesis of 2,4-diacylpyrroles by direct acylation of pyrrole and 2- and 3-acylpyrroles is reported.Among these, Friedel-Crafts acylation of 3-acylpyrroles is the most general and advantageous method because it utilises easily accessible starting materials.In addition it is always regiospecific and readily provides 2,4-diacylpyrroles containing identical or different acyl groups in very high yields (81-100percent) under mild conditions, Alternative procedures concern the synthesis of precursors of 2,4-diacylpyrroles containing one or two acyl groups masked by a 1,3-benzodithiolyl or 1,3-benzoxathiolyl group and subsequent hydrolysis with HgO-35percent aq.HBF4-Me2SO.Overall yields are always good (52-60percent).Indirect acylation constitutes a secure complement to direct acylation when it is necessary to operate in the presence of protected acyl groups.
2-SUBSTITUTED 1,3-BENZODITHIOLIUM TETRAFLUOROBORATES AS USEFUL ACYLATING AGENTS OF PYRROLE
Barbero, Margherita,Cadamuro, Silvano,Degani, Iacopo,Dughera, Stefano,Fochi, Rita,et al.
, p. 619 - 627 (2007/10/02)
A comparative study on the acylation of pyrrole by utilizing 2-substituted 1,3-benzodithiolium tetrafluoroborates instead of 2-substituted 1,3-benzoxathiolium tetrafluoroborates has been accomplished.The use of 2-substituted 1,3-benzodithiolium tetrafluoroborates proved to be more convenient since it gives higher yields of 2-acylpyrroles (58-90percent) and appears of larger applicability for the preparation of symmetrical and unsymmetrical 2,5-diacylpyrroles which were obtained in most cases in quantitative yields.
