173322-55-9

Upstream product

• 109-97-7 pyrrole 
• 104-87-0 4-methyl-benzaldehyde 
• 1167990-37-5 C₃₀H₃₁N₃O₄S₂ 
• 1167990-47-7 C₄₂H₃₉N₃O₄S₂ 
• 179811-44-0 2,5-Bis-(2-p-tolyl-benzo[1,3]oxathiol-2-yl)-1H-pyrrole 
• 132371-60-9 2,5-bis(4-toluyl)pyrrole 
• 173322-53-7 2,5-bis[α-hydroxy-α-(4-methylphenyl)]methylpyrrole 

Downstream Products

• 1558048-25-1 methoxo(5,10-ditolylsubporphyrinato)boron(III) 

Relevant academic research and scientific papers

Fusing Porphyrins and Phospholes: Synthesis and Analysis of a Phosphorus-Containing Porphyrin

A phosphole-fused porphyrin dimer, as a representative of a new class of porphyrins with a phosphorus atom, was synthesized for the first time. The porphyrin dimer exhibits remarkably broadened absorption, indicating effective π-conjugation over the two porphyrins through the phosphole moiety. The porphyrin dimer possesses excellent electron-accepting character, which is comparable to that of a representative electron-accepting material, [60]PCBM. These results provide access to a new class of phosphorus-containing porphyrins with unique optoelectronic properties.

Rational synthesis of tripyrranes

(Chemical Equation Presented) The rational, chromatography-free synthesis of two regioisomeric 5,10-diaryltripyrranes from pyrrole and aromatic acids has been developed. The strategy is general and should be applicable to a broad range of acids. This meth

Cycloaddition reaction of benzoheteroazepine: Synthesis of 4a,5,6,12-tetrahydro-1H-1,3-oxazino[3,2-d][1,5] benzothiazepin-1-ones and 1H,7H-1,3-oxazino[3,2-d][1,5] benzodiazepin-1-ones

2,3-Dihydro-1,5-benzothiazepines and 2,3-dihydro-1H-1,5-benzodiazepines reacted with α -carbonylketenes, generated from 2-diazo-1,3-diphenyl-1,3-propanedione and 2-diazo-1-phenyl-1,3-butandione by heating, to give [2+4] cycloadducts 4a,5,6,12-tetrahydro-1H-1,3-oxazinop[3,2-d] [1,5]-benzothiazepin-1-ones and 4a,5,6,12-tetrahydro-1H,7H-1,3-oxazino [3,2-d][1,5]-benzodiazepin-1-ones. The cycloaddition reactions showed different regioselectivities when different 1,5-benzoheteroazepines reacted with asymmetric 2-diazo-1-phenyl-1,3-butandione. The conformations of cycloadducts and cycloadducts reaction mechanism were described.

Stepwise syntheses of core-modified, meso-substituted porphyrins

Simple conditions are discovered to afford modified tripyrrin derivatives by condensation of 2,5-bis(α-hydroxymethyl)pyrrole, thiophene and furan derivatives with pyrrole in the presence of acid catalyst. The core-modified porphyrins were synthesized by acid catalyzed 3+1 condensation of modified tripyrrins with 2,5-bis(α-hydroxymethyl)-substituted pyrrole, thiophene or furan. This new process gives a single porphyrin isomer and overcomes the synthetic problems associated with separation and purification of regioisomeric mixtures.