1323977-19-0Relevant academic research and scientific papers
Selective palladium-catalyzed C-F activation/carbon-carbon bond formation of polyfluoroaryl oxazolines
Yu, Daohong,Shen, Qilong,Lu, Long
supporting information; experimental part, p. 1798 - 1804 (2012/04/04)
A selective palladium-catalyzed Suzuki-Miyaura coupling reaction of polyfluorophenyl oxazolines through ortho C-F activation is described. It was found that reactions with DPPF as the ligand occurred much faster than those with other ligands. A variety of arylboronic acids including challenging functionalized arylboronic acids such as enolizable ketones, aldehyde, cyano, ester, and trifluoromethyl groups were tolerated with the reaction conditions.
Exploration of the scope of Pt-catalyzed C-F activation
Keyes, Lauren,Sun, Alex D.,Love, Jennifer A.
supporting information; experimental part, p. 3985 - 3994 (2011/09/15)
We recently reported methods for the catalytic methylation and methoxylation of polyfluoroaryl imines utilizing [Pt2Me 4(SMe2)2] as a precatalyst. These methodologies provide a novel route to partially functiona
