1324005-81-3Relevant academic research and scientific papers
Reaction of frustrated lewis pairs with conjugated ynones-selective hydrogenation of the carbon-carbon triple bond
Xu, Bao-Hua,Kehr, Gerald,Froehlich, Roland,Wibbeling, Birgit,Schirmer, Birgitta,Grimme, Stefan,Erker, Gerhard
, p. 7183 - 7186 (2011/09/30)
Frustrated, but not frustrating: Frustrated Lewis pairs (FLPs) can undergo selective 1,4-addition reactions with conjugated ynones (see scheme). Upon FLP dihydrogen activation selective hydrogenation of the carbon-carbon triple bond can be achieved, in one case even catalytically. Copyright
