132430-41-2Relevant academic research and scientific papers
The Dithiole Series. Part 8. Synthesis of Ring-fused 1,2-Dithiolylium and Isothiazolium Salts from Complexes containing Cyclopalladated Ligands
Davis, Robert C.,Grinter, Trevor J.,Leaver, Derek,O'Neil, Robert M.,Thomson, Gordon A.
, p. 2881 - 2887 (1990)
Ring-fused 1,2-dithiolylium or isothiazolium salts were obtained by substitution of a sulphur atom for the grouping (R2NCS2Pd) in various cyclopalladated complexes derived from ligands (LH) containing Ar-C=S or Ar-C=N- substructures.This process was accomplished by reaction of the complexes with: (a), thiocyanogen (yielding an intermediate metal-free thiocyanatocompound) followed by perchloric acid, or (b), morpholine-N-sulphenyl chloride.
