The Dithiole Series. Part 8. Synthesis of Ring-fused 1,2-Dithiolylium and Isothiazolium Salts from Complexes containing Cyclopalladated Ligands

DOI: 10.1039/P19900002881

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2881 - 2887 (1990)

Update date:2022-08-02

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Authors:

Davis, Robert C.

Grinter, Trevor J.

Leaver, Derek

O'Neil, Robert M.

Thomson, Gordon A.

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Article abstract of DOI:10.1039/P19900002881

Ring-fused 1,2-dithiolylium or isothiazolium salts were obtained by substitution of a sulphur atom for the grouping (R2NCS2Pd) in various cyclopalladated complexes derived from ligands (LH) containing Ar-C=S or Ar-C=N- substructures.This process was accomplished by reaction of the complexes with: (a), thiocyanogen (yielding an intermediate metal-free thiocyanatocompound) followed by perchloric acid, or (b), morpholine-N-sulphenyl chloride.

Full text of DOI:10.1039/P19900002881

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