132475-59-3Relevant academic research and scientific papers
A CATALYTIC EFFECT OF ZnCl2 DURING DIBAL REDUCTION OF β-KETOSULFOXIDES
Solladie-Cavallo, A.,Suffert, J.,Adib, A.,Solladie, G.
, p. 6649 - 6652 (1990)
High asymmetric inductions (>94/6) are obtained upon DIBAL reduction of β-ketosulfoxides in the presence of non-stoichiometric amounts of ZnCl2 (0.5 equiv. to 0.05 equiv.).Intramolecular hydride transfer and new chelated models are proposed to explain the
