Tetrahedron Letters p. 6649 - 6652 (1990)
Update date:2022-09-26
Topics:
Solladie-Cavallo, A.
Suffert, J.
Adib, A.
Solladie, G.
High asymmetric inductions (>94/6) are obtained upon DIBAL reduction of β-ketosulfoxides in the presence of non-stoichiometric amounts of ZnCl2 (0.5 equiv. to 0.05 equiv.).Intramolecular hydride transfer and new chelated models are proposed to explain the
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