132475-74-2

Upstream product

• 540-63-6 ethane-1,2-dithiol 
• 106281-44-1 (6-oxocyclohex-1-en-1-yl)methyl acetate 
• 76047-55-7 2--2-cyclohexenone 
• 113526-04-8 2-(nitromethyl)-cyclohex-1-ene-3-one 
• 930-68-7 cyclohexenone 
• 23851-06-1 disodium 1,2-ethanedithiolate 
• 125066-15-1 2-(phenylsulfonylmethyl)cyclohexenone 

Relevant academic research and scientific papers

Regioselective S -allylation of thiols with cyclic Baylis-Hillman acetates

An efficient and mild S-allylation of thiols with cyclic Baylis-Hillman acetates with no need of a transition-metal-catalyst or an expensive additive is described. Allyl sulfides are prepared in good to excellent yields (60-97%) and a single regioisomer was observed in all cases.

Regioselective replacement of nitro or sulfonyl group in cyclic α-(nitroalkyl)- or α-(phenylsulfonylalkyl)enones by nucleophiles

Cyclic α-(nitroalkyl)enones and α-(phenylsulfonylalkyl)enones undergo regioselective substitution of the nitro group by relatively soft sulfur, nitrogen and carbon nucleophiles.