76047-55-7

Upstream product

• 50-00-0 formaldehyd 
• 930-68-7 cyclohexenone 
• 108-98-5 thiophenol 
• 107454-83-1 1-(nitromethyl)-1,2-epoxycyclohexane 
• 105956-40-9 2-(hydroxymethyl)cyclohex-2-en-1-one 
• 927434-10-4 2-bromomethylcyclohex-2-enone 
• 106281-44-1 (6-oxocyclohex-1-en-1-yl)methyl acetate 
• 108-94-1 cyclohexanone 
• 930-69-8 sodium thiophenolate 
• 125066-15-1 2-(phenylsulfonylmethyl)cyclohexenone 
• 113526-04-8 2-(nitromethyl)-cyclohex-1-ene-3-one 

Downstream Products

• 75731-84-9 cis-2-ethyl-3-methylcyclohexanone 
• 75731-83-8 trans-2-ethyl-3-methylcyclohexanone 
• 125066-03-7 2-Cyano-2-(6-oxo-cyclohex-1-enylmethyl)-butyric acid ethyl ester 
• 125066-15-1 2-(phenylsulfonylmethyl)cyclohexenone 
• 139294-22-7 2--2-cyclohexene-1-ol 
• 139294-30-7 Malonic acid ethyl ester 2-phenylsulfanylmethyl-cyclohex-2-enyl ester 
• 139294-46-5 9-Methylene-3-oxo-4-phenylsulfanyl-2-oxa-bicyclo[3.3.1]nonane-4-carboxylic acid ethyl ester 
• 139294-38-5 2-Diazo-malonic acid ethyl ester 2-phenylsulfanylmethyl-cyclohex-2-enyl ester 
• 132929-62-5 2-(pyrrolidin-1-ylmethyl)cyclohex-2-en-1-one 
• 132475-88-8 2-(2-Methyl-2-nitro-propyl)-cyclohex-2-enone 
• 132475-86-6 2-(2-nitropropyl)cyclohex-2-en-1-one 
• 132475-90-2 3-Hydroxy-5,5-dimethyl-2-(6-oxo-cyclohex-1-enylmethyl)-cyclohex-2-enone 
• 132475-84-4 3-oxo-2-(6-oxo-cyclohex-1-enylmethyl)butyric acid methyl ester 
• 77407-04-6 2-(6-oxo-cyclohex-1-enylmethyl)malonic acid dimethyl ester 

Relevant academic research and scientific papers

A Metal-Free Synthesis of 2-Alkyl(or Aryl) Thiomethyl-2-cyclohexenones from Cyclic Morita–Baylis–Hillman Bromides

Under mild conditions, an efficient and rapid S-allylation of thiols with cyclic Morita–Baylis–Hillman (MBH) bromides without the need of a transition-metal catalyst or an expensive additive is described herein. Treatment of the MBH bromides with various

Regioselective S -allylation of thiols with cyclic Baylis-Hillman acetates

An efficient and mild S-allylation of thiols with cyclic Baylis-Hillman acetates with no need of a transition-metal-catalyst or an expensive additive is described. Allyl sulfides are prepared in good to excellent yields (60-97%) and a single regioisomer was observed in all cases.

Reactions of 2-phenylthio-2-cycloalkenones and 2-[phenyl(thiomethyl)]-2-cycloalkenones. Synthesis of some useful chiral and achiral intermediates

The allyl acetates derived from 2-phenylthio-2-cyclopentenone, 2-phenylthio-2-cyclohexenone, 2-[phenylthio(methyl)]-2-cyclopentenone and 2-[phenylthio(methyl)]-2-cyclohexenone have been hydrolysed by pig liver acetone powder to obtain the corresponding al

An Efficient and Convenient Synthesis of Bridged δ-Lactones

endo-4-Ethoxycarbonyl-4-(phenylthio)-9-methylene-2-oxabicyclononan-3-ones (5a-c) and their related compounds 5e-h, and endo-4-ethoxycarbonyl-4-(phenylthio)-8-methylene-2-oxabicyclooctan-3-one (5d) were synthesized from α-diazomalonates 3 of 2-(phenylthio)cyclohex-2-en-1-ols (1a-c) and their related compounds 1e-h, and 2-(phenylthio)cyclopent-2-en-1-ol (1d), respectively, via the sigmatropic rearrangement of cyclic allylsulfonium ylides 4.

Regioselective replacement of nitro or sulfonyl group in cyclic α-(nitroalkyl)- or α-(phenylsulfonylalkyl)enones by nucleophiles

Cyclic α-(nitroalkyl)enones and α-(phenylsulfonylalkyl)enones undergo regioselective substitution of the nitro group by relatively soft sulfur, nitrogen and carbon nucleophiles.

NEW SUBSTITUTION REACTION OF ALLYLIC NITRO COMPOUNDS. REGIOSELECTIVE REPLACEMENT OF NITRO GROUP IN CYCLIC α-(NITROALKYL)ENONES BY NUCLEOPHILES

Regioselective replacement of nitro group in cyclic α-(nitroalkyl)-enones by various nucleophiles such as stabilized carbanions, amine, NaN3, PhSO2Na and PhSNa provides the overall SN2 type products.