132475-88-8

Upstream product

• 147225-22-7 2-lithio-2-nitropropane 
• 113526-04-8 2-(nitromethyl)-cyclohex-1-ene-3-one 
• 125066-15-1 2-(phenylsulfonylmethyl)cyclohexenone 
• 930-68-7 cyclohexenone 
• 79-46-9 2-nitropropane 
• 105956-40-9 2-(hydroxymethyl)cyclohex-2-en-1-one 
• 76047-55-7 2--2-cyclohexenone 

Relevant academic research and scientific papers

The first DMAP-mediated palladium-free Tsuji-Trost-type reaction of cyclic and acyclic Baylis-Hillman alcohols with active methylene compounds

Direct allylic substitution of cyclic Baylis-Hillman alcohols with active methylene compounds under modified Taber's conditions (DMAP, toluene, reflux, 4 ? molecular sieves), with no Pd catalysts/activating agents, as is usually required for the process, affords the C-allylation products in moderate to good yields.

Regioselective replacement of nitro or sulfonyl group in cyclic α-(nitroalkyl)- or α-(phenylsulfonylalkyl)enones by nucleophiles

Cyclic α-(nitroalkyl)enones and α-(phenylsulfonylalkyl)enones undergo regioselective substitution of the nitro group by relatively soft sulfur, nitrogen and carbon nucleophiles.