132486-03-4Relevant articles and documents
Archibald, E. H.,Hooley, J. G.,Phillips, N.
, p. 70 - 70 (1936)
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Duval, Therese,Duval, Clement
, p. 110 - 114 (1948)
With the aid of the chevenard thermobalance the authors have traced the pyrolysis curve of the following compounds of rubidium : chloride, perchlorate, sulphate, hexanitritocobaltate, hexachlorostannate, hexachloroplatinate; they have determined the ternperatures of commencement of dissociation of these substances, shown the different behaviour of the neutral and the acid sulphates, and demonstrated that the hexamtritocobaltate (colialtinitrite) cannot be employed for gravimetric analysis and the hexachlorostannate (stannichloride) requires a special method of preparation in order to give accurate results.
Blazejowski, Jerzy,Szychlinski, Jerzy,Windorpska, Krystyna
, p. 147 - 166 (1981)
Study of the temperature effect on the process of rubidium hexachlorotellurite decomposition
Lyakh,Sizyakov,Zaitsev,Pigova,Ugolkov
, p. 1507 - 1509 (2011/05/07)
Thermal dissociation of rubidium hexachlorotellurite in inert atmosphere (argon) and in atmosphere with air access was studied. The DTG and DTA curves for the process of rubidium hexachlorotellurite thermal dissociation in the argon atmosphere are given. Their character is defined by the behavior of TeCl4, which is liberated on the decomposition of samples.
A New Route to Alkali Metal Aluminum Hydrides MAlH4 with M = Na, K, Rb, Cs and Structural Features for The Whole Family with M = Li to Cs.
Bastide, J. P.,Hajri, J. El,Claudy, P.,Hajbi, A. El
, p. 1037 - 1048 (2008/10/09)
MAlH4 with M = Na, K, Rb and Cs were prepared in toluene or hexane from an exchange reaction between LiAlH4 and an halide of the corresponding metal dissolved in the medium as Ziegler-type complex with triethylaluminum. The best process involves the equimolar complexes MF-AlEt3 with fluorides. The four MAlH4 were quantitatively obtained with a purity > 99% (wt). RbAlH4 and CsAlH4 have the same barite-type structure as KAlH4 (orthorhombic, Z = 4), with parameters (?, .+-..002) a:b:c : 9.253:5.950:7.599; 9.981:6.075:7.953, respectively.