1325236-25-6

Basic information

• Product Name: [5-amino-4-(4,4-dimethyl-3,4,5,6-tetrahydropyrimidin-2-yl)imidazolium⁽²⁺⁾][ZnCl₄]
• Synonyms: [5-amino-4-(4,4-dimethyl-3,4,5,6-tetrahydropyrimidin-2-yl)imidazolium⁽²⁺⁾][ZnCl₄]
• CAS NO: 1325236-25-6
• Molecular Weight: 402.469
• Mol File: 1325236-25-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [5-amino-4-(4,4-dimethyl-3,4,5,6-tetrahydropyrimidin-2-yl)imidazolium⁽²⁺⁾][ZnCl₄](CAS DataBase Reference)
• NIST Chemistry Reference: [5-amino-4-(4,4-dimethyl-3,4,5,6-tetrahydropyrimidin-2-yl)imidazolium⁽²⁺⁾][ZnCl₄](1325236-25-6)
• EPA Substance Registry System: [5-amino-4-(4,4-dimethyl-3,4,5,6-tetrahydropyrimidin-2-yl)imidazolium⁽²⁺⁾][ZnCl₄](1325236-25-6)

Safety Data

• Hazardous Substances Data: 1325236-25-6(Hazardous Substances Data)

Upstream product

• 7647-01-0 hydrogenchloride 
• 2365-40-4 N₆-(2-isopentenyl)adenine 

Relevant articles and documents

Transformations of the natural cytokinin N6-isopentenyladenine in aqueous acidic media: Structural aspects

N6-Isopentenyladenine (L1) was subjected to variously acidic media in 0.1 M, 1 M and 2 M HCl. In dependence on the acidity of the medium, the formation of three main acid hydrolysis products, involving the N6-isopentenyladeninium (HL1) (1), 7,8,9,10-tetrahydro-7,7-dimethyl-3H-pyrimido[2,1-i]purin-6-ium (HL2) (2) or 5-amino-4-(4,4-dimethyl-3,4,5,6-tetrahydropyrimidin-2-yl)-imidazolium (H2L3) (3-5) cations, were determined and characterized by multinuclear solution-state NMR spectroscopy and in the solid state by single crystal X-ray analysis. The coordination abilities of these transformation products have been also investigated. The compounds of the compositions [Zn(HL1)Cl3]·H2O (1), [Zn3(HL2) 2Cl8] (2), (H2L3)[CuCl4] (4) and (H2L3)[ZnCl4] (5) have been prepared in dependence on the acidity of the medium used by the reactions of L1 with ZnCl2· 1.5H2O or CuCl2·2H2O. Based on the NMR spectroscopic and X-ray crystallographic results, the mechanism of transformation of L1 in the acidic medium, involving the protonation, cyclization and ring fission, has been suggested. The Royal Society of Chemistry 2011.