132541-12-9Relevant academic research and scientific papers
A general and efficient strategy for 7-aryloctahydroindole and cis-3a-aryloctahydroindole alkaloids: Total syntheses of (±)-γ- lycorane and (±)-crinane
Gao, Shuanhu,Tu, Yong Qiang,Song, Zhenlei,Wang, Aixia,Fan, Xiaohui,Jiang, Yijun
, p. 6523 - 6525 (2007/10/03)
A general and efficient approach to both 7-aryloctahydroindole and cis-3a-aryloctahydroindole alkaloids has been developed. The key step involves Michael additions of the corresponding kinetics and thermodynamics lithium enolates of ketone 9 to the versat
Syntheses of (+/-)-α- and (+/-)-γ-Lycorane via a Stereocontrolled Organopalladium Route
Baeckvall, Jan-E.,Andersson, Pher G.,Stone, Guy B.,Gogoll, Adolf
, p. 2988 - 2993 (2007/10/02)
Total syntheses of (+/-)-α- and (+/-)-γ-lycorane are described.The key steps in the syntheses are the stereocontrolled palladium-catalyzed intramolecular 1,4-chloroamidation of 12 to 13 and the subsequent anti-stereoselective copper-catalyzed SN/sub
