144344-97-8

Upstream product

• 6642-34-8 6-bromopiperonyl alcohol 
• 141091-07-8 (3-Benzo[1,3]dioxol-5-yl-cyclohex-2-enyl)-acetaldehyde 
• 141090-98-4 3-<3,4-(methylenedioxy)phenyl>-2-cyclohexen-1-ol 
• 116033-82-0 1-Lithio-3,4-(methylenedioxy)benzene 
• 144412-86-2 1-<2-<<(tert-Butyldimethylsilyl)oxy>methyl>-4,5-(methylenedioxy)phenyl>-3-<(ethoxycarbonyl)methyl>cyclohex-1-ene 
• 144412-85-1 1-<2-<<(tert-Butyldimethylsilyl)oxy>methyl>-4,5-(methylenedioxy)phenyl>-3-acetoxycyclohex-1-ene 
• 144412-84-0 1-<2-<<(tert-Butyldimethylsilyl)oxy>methyl>-4,5-(methylenedioxy)phenyl>-2-cyclohexen-1-ol 
• 144412-87-3 1-<2-<<(tert-Butyldimethylsilyl)oxy>methyl>-4,5-(methylenedioxy)phenyl>-3-(2-hydroxyethyl)cyclohex-1-ene 
• 144412-83-9 1-<2-(Hydroxymethyl)-4,5-(methylenedioxy)phenyl>-2-cyclohexen-1-ol 
• 141090-97-3 1-<3,4-(Methylenedioxy)phenyl>-3-<(ethoxycarbonyl)methyl>cyclohex-1-ene 
• 144412-88-4 1-<2-<<(tert-Butyldimethylsilyl)oxy>methyl>-4,5-(methylenedioxy)phenyl>-3-(2-azidoethyl)cyclohex-1-ene 
• 153446-37-8 1-<3,4-(Methylenedioxy)phenyl>-3-(2-methanesulfonyloxyethyl)cyclohex-1-ene 
• 144412-93-1 1-<3,4-(Methylenedioxy)phenyl>-3-(2-hydroxyethyl)cyclohex-1-ene 

Downstream Products

• 132541-12-9 (3aR*,7S*,7aS*)-1-(Benzyloxycarbonyl)-7-<3,4-(methylenedioxy)phenyl>-2,3,3a,4,5,6,7,7a-octahydro-1H-indole 

Relevant academic research and scientific papers

Intramolecular schmidt reactions of azides with carbocations: Synthesis of bridged-bicyclic and fused-bicyclic tertiary amines

Aliphatic azides were captured intramolecularly by carbocations, producing aminodiazonium ion intermediates. Carbon-to-nitrogen rearrangement then occurred, generating bridged- or fused-bicyclic α-amino carbocations or iminium ions, depending on the geome

An Intramolecular Schmidt Reaction of an Alkyl Azide with a Carbocation. The Generation and Rearrangement of a Conformationally Restricted Secondary Aminodiazonium Ion

Treatment of azidoalkene 2 with triflic acid produced the bridged bicyclic enamine 3 by an intramolecular Schmidt reaction.Rearrangement of the intermediate aminodiazonium ion 5 is completely regioselective.