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Upstream product

• 64-17-5 ethanol 
• 98394-23-1 N-(2-bromo-2-methyl-1-phenyl-1-propylidene)isopropylamine 
• 98394-23-1 [2-Bromo-2-methyl-1-phenyl-prop-(E)-ylidene]-isopropyl-amine 
• 67-63-0 isopropyl alcohol 
• 10409-54-8 2-bromo-2-methyl-1-phenyl-propan-1-one 

Relevant academic research and scientific papers

Silver ion induced reactions of α-haloimines

The silver ion induced reactions of α-haloimines are markedly different from similar reactions with the corresponding α-haloketones. The various reactions of α-haloimines, including α-alkoxylation 1,2-dehydrohalogenation, rearrangement via α-alkoxyaziridines, Favorskii-rearrangement and Wagner Meerwein rearrangement, are compared and evaluated with silver-induced reactions of α-haloketones The silver ion assisted reactions of α-haloimines are best interpreted in terms of the intermediacy c α-imidoylcarbenium ions or pseudo-α-imidoylcarbenium ions.

DEHYDRODIMERIZATION OF IMINES VIA α-BROMOIMINES USING LITHIUM DIISOPROPYLAMIDE

α-Bromoimines were transformed into 1,4-diimines under soft conditions using lithium diisopropylamide in tetrahydrofuran.