1325760-56-2

Basic information

• Product Name: 5-phenyl-1,4-bis-triphenylphosphinegold(I) 1,2,3-triazolate
• CAS NO: 1325760-56-2
• Molecular Weight: 1061.66
• Mol File: 1325760-56-2.mol

Chemical Properties

• CAS DataBase Reference: 5-phenyl-1,4-bis-triphenylphosphinegold(I) 1,2,3-triazolate(CAS DataBase Reference)
• NIST Chemistry Reference: 5-phenyl-1,4-bis-triphenylphosphinegold(I) 1,2,3-triazolate(1325760-56-2)
• EPA Substance Registry System: 5-phenyl-1,4-bis-triphenylphosphinegold(I) 1,2,3-triazolate(1325760-56-2)

Safety Data

• Hazardous Substances Data: 1325760-56-2(Hazardous Substances Data)

Upstream product

• 20224-83-3 PPh₃Au^IC₈H₅ 

Relevant articles and documents

Inorganic click (iClick) synthesis of heterotrinuclear Pt II/AuI2 complexes

Metal-azide-metal-acetylide cycloaddition (iClick) reactions to synthesize heterotrimetallics and an unexpected novel tetranuclear gold(i) complex, are described. In addition, a discussion regarding the connection between traditional azide-alkyne cycloaddition reactions and iClick is presented focusing on applications towards linking multiple metal ions.

Excited-State Turn-On of Aurophilicity and Tunability of Relativistic Effects in a Series of Digold Triazolates Synthesized via iClick

iClick reactions between Au(I) acetylides PPh3Au-CCR, where R = nitrophenyl (PhNO2), phenyl (Ph), thiophene (Th), bithiophene (biTh), and dimethyl aniline (PhNMe2), and Au(I)-azide PPh3AuN3 provide di

Au-iClick mirrors the mechanism of copper catalyzed azide-alkyne cycloaddition (CuAAC)

This report outlines the investigation of the iClick mechanism between gold(i)-azides and gold(i)-acetylides to yield digold triazolates. Isolation of digold triazolate complexes offer compelling support for the role of two copper(i) ions in CuAAC. In add

METHOD FOR LINKING TWO OR MORE METALS FOR PHOTO AND ELECTRONIC MATERIALS

Embodiments of the invention are directed to bimetallic substituted triazole compounds and methods to prepare the compounds. The compounds include at least one 1,2,3 -triazole that is substituted by two metal ions in the 1 and 4 or 5 position of the triaz

Toward permetalated alkyne/azide 3 + 2 or "click" cycloadducts

The Cu(I)-catalyzed reaction of the platinum butadiynyl complex trans-(C6F5)(p-tol3P)2Pt(C≡C) 2H and rhenium cyclopentadienylazide complex (η5- C5H4N3)Re(CO)3 yields the 1,2,3-triazole trans-(C6F5)(p-tol3P) 2PtC≡CC=CHN((η5-C5H 4)Re(CO)3)N=N (54%), which upon treatment with Re(CO) 5OTf or Re(CO)5Br affords Re(CO)5 +TfO- or cis-Re(CO)4Br adducts derived from attack at N(3) (84-98%). The crystal structures of solvates of these three complexes are compared, but attempts to metalate the =CH groups were unsuccessful. However, the reaction of monometallic trans-(C6F 5)(p-tol3P)2PtC≡CC=CHN(CH 2C6H5)N=N and MeI gives an N(3)-methyl triazolium salt (81%), which upon addition of Ag2O and [RhCl(cod)]2 yields the N-heterocyclic carbene complex trans-(C 6F5)(p-tol3P)2PtC≡CC ...C(RhCl(cod))...N(CH2C6H 5)...N...N(Me). Further experiments and analyses suggest that =CH derivatization is possible only when the 1H NMR chemical shift is downfield of ca. δ 7.9 ppm. Electropositive metal fragments generally effect upfield shifts, meaning that insulating spacers, electronegative ligands, and/or new chemical methodologies will be required to construct tetrametallic arrays via click chemistry.

1,3-Dipolar cycloaddition between a metal-azide (Ph3PAuN 3) and a metal-acetylide (Ph3PAuCCPh): An inorganic version of a click reaction

This report describes the synthesis and characterization of 1,5-bis-triphenylphosphinegold(i) 1,2,3-triazolate (3(1,5)). The synthesis of the dinuclear complex 3(1,5) is achieved via an unprecedented inorganic click (iClick) reaction