132607-79-5Relevant academic research and scientific papers
Palladium triggered diene formation from nitro allylic compounds: A versatile entry into naphthalene derivatives
Kerim, Mansour Dolè,Jia, Shuanglong,Theodorakidou, Chrysoula,Prévost, Sébastien,El Ka?m, Laurent
, p. 10917 - 10920 (2018)
Nitro allylic derivatives were converted into dienes through the elimination of the nitro group under basic treatment, in the presence of a palladium catalyst. This reaction probably involves the formation of a palladium π-allyl complex followed by a base-promoted β-hydride elimination. This reaction, combined with the condensation of ketones with nitromethane and the functionalization of the resulting nitrocycloalkenes, constitutes a very powerful synthetic tool for the formation of dienes. Particular attention has been brought to the application of this methodology to the formation of 1-substituted naphthalenes from 1-tetralone.
Grignard reaction of substituted nitromethanes: The nwe observations
Gupta, Ramesh Chandra,Seth, M,Bhaduri, A P
, p. 745 - 747 (2007/10/02)
Reactions of 1-(1-nitromethyl)cyclohexene and its derivatives with excess of methylmagnesium iodide have been studied.In a few cases a chemoselective attack on the nitro group by the Grignard reagent has been observed.The N,N-dialkylhydroxylamine, the nor
