132610-70-9Relevant academic research and scientific papers
Some Properties of Cyclopropenone Oximes under Beckmann Reaction Conditions
Yoshida, Hiroshi,Yoshida, Keisuke,Totani, Hiroyuki,Ogata, Tsuyoshi,Matsumoto, Kiyoshi
, p. 3579 - 3582 (2007/10/02)
The reaction of diphenylcyclopropenone oxime (1a) with acetyl or tosyl isocyanate, carboxylic anhydrides, or nitrohalobenzenes yielded the cyclopropenone O-substituted oxime derivatives.Treating with thionyl bromide and chloride 1a gave 3-haloacrylonitriles.Whereas 1a as well as other cyclopropenone oximes, were stable under acidic conditions, heating in methanolic sodium hydroxide gave the ring-opened α,α-dimethoxyketones oximes.
