13264-91-0

Basic information

• Product Name: 2-Nitrophenyl2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-a-D-glucopyranoside
• Synonyms: 2-Nitrophenyl2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-a-D-glucopyranoside;2-Nitrophenyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-α-D-glucopyranoside;o-Nitrophenyl 2-AcetaMido-2-deoxy-α-D-glucopyranoside Triacetate;o-Nitrophenyl 2-acetamido-2-deoxy-alpha-D-glucopyranoside triacetate
• CAS NO: 13264-91-0
• Molecular Formula: C20H24N2O11
• Molecular Weight: 468.41
• EINECS: 1533716-785-6
• Product Categories: Carbohydrates & Derivatives
• Mol File: 13264-91-0.mol
• Article Data: 3

Chemical Properties

• Melting Point: 173-174°C
• Boiling Point: 649.5±55.0 °C(Predicted)
• Appearance: /
• Density: 1.37±0.1 g/cm3(Predicted)
• PKA: 13.35±0.70(Predicted)
• CAS DataBase Reference: 2-Nitrophenyl2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-a-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Nitrophenyl2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-a-D-glucopyranoside(13264-91-0)
• EPA Substance Registry System: 2-Nitrophenyl2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-a-D-glucopyranoside(13264-91-0)

Safety Data

• Hazardous Substances Data: 13264-91-0(Hazardous Substances Data)

Usage

Chemical Properties

White Crystalline Solid

Uses

o-Nitrophenyl 2-Acetamido-2-deoxy-3,4,6-tri-O-acetyl-α-D-glucopyranoside (cas# 13264-91-0) is a compound useful in organic synthesis.

Upstream product

• 88-75-5 2-hydroxynitrobenzene 
• 3068-34-6 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-chloro-tetrahydro-pyran-4-yl ester 
• 3006-60-8 1,3,4,6-tetra-O-acetyl-2-acetamido-2-deoxy-α,β-D-mannopyranose 
• 4148-73-6 phenyl 2-acetamido-2-deoxy-3,4,6-tri-O-acetyl-α-D-mannopyranoside 
• 72-87-7 N-acetyl-D-mannosamine 
• 10378-06-0 2-methyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-β-D-mannopyrano)-[2,1:4',5']-2-oxazoline 
• 3006-60-8 Acetic acid (2R,3R,4R,5S,6R)-2,5-diacetoxy-6-acetoxymethyl-3-acetylamino-tetrahydro-pyran-4-yl ester 
• 3006-60-8 2-acetamido-1,3,4,6-tetra-O-acetyl-2-deoxy-β-D-glucopyranose 
• 10034-19-2 1,3,4,6-tetra-O-acetyl-2-amino-2-deoxy-α-D-glucopyranose hydrochloride 

Downstream Products

• 78341-33-0 isopropyl 2-acetamido-2-deoxy-β-D-glucopyranoside 

Relevant articles and documents

Facile synthesis of nitrophenyl 2-acetamido-2-deoxy-α-D- mannopyranosides from ManNAc-oxazoline

The synthetic procedures for a large-scale preparation of o- and p-nitrophenyl 2-acetamido-2-deoxy-α-D-mannopyranoside are described. The synthetic pathway employs the glycosylation of phenol with ManNAc oxazoline, followed by nitration of the aromatic moiety yielding a separable mixture of the o- and p-nitrophenyl derivative in a 2:3 ratio.

Synthesis of N-Acetylglucosamine Aryl β-Glycosides Catalyzed by Crown Compounds

Glycosylation of various phenols with α-D-glucosaminyl chloride peracetate in a solid phase-liquid system catalyzed by crown compounds was studied. The highest yields of aryl β-glycosides were observed at room temperature in acetonitrile using anhydrous p