132658-83-4

Upstream product

• 4746-97-8 cyclohexanedione monoethylene ketal 
• 1517-82-4 (-)-menthyl p-toluenesulfinate 

Downstream Products

• 132658-84-5 (7S,8R)-7-((R)-Toluene-4-sulfinyl)-1,4-dioxa-spiro[4.5]decan-8-ol 
• 132746-90-8 (7S,8S)-7-((R)-Toluene-4-sulfinyl)-1,4-dioxa-spiro[4.5]decan-8-ol 
• 132658-87-8 (S)-4-benzyloxy-2-cyclohexen-1-one 
• 132658-86-7 (7S,8S)-8-Benzyloxy-7-((R)-toluene-4-sulfinyl)-1,4-dioxa-spiro[4.5]decane 
• 132746-89-5 (+)-(R)-4-hydroxycyclohex-2-enone 
• 121652-00-4 (S)-(-)-4-hydroxy-2-cyclohexan-1-one 
• 132658-89-0 (R)-4-acetoxy-2-cyclohexen-1-one 
• 132513-02-1 (S)-(-)-4-acetoxy-2-cyclohexen-1-one 
• 132658-85-6 Acetic acid (7S,8R)-7-((R)-toluene-4-sulfinyl)-1,4-dioxa-spiro[4.5]dec-8-yl ester 
• 132658-85-6 Acetic acid (7S,8S)-7-((R)-toluene-4-sulfinyl)-1,4-dioxa-spiro[4.5]dec-8-yl ester 

Relevant academic research and scientific papers

ASYMMETRIC SYNTHESIS OF (R) AND (S)-4-HYDROXY-2-CYCLOHEXENONE AND DERIVATIVES

The asymmetric syntheses of both enantiomers of 4-hydroxy-2-cyclohexenone and their O-acyl and O-benzyl derivatives are reported.DIBAL and ZnCl2/DIBAL stereoselective reductions of the ketosulfoxides resulting in the sulfinylation of 1,4-cyclohexanedione