132658-83-4Relevant articles and documents
ASYMMETRIC SYNTHESIS OF (R) AND (S)-4-HYDROXY-2-CYCLOHEXENONE AND DERIVATIVES
Carreno, M. Carmen,Ruano, Jose L. Garcia,Garrido, Mercedes,Ruiz, M. Pilar,Solladie, Guy
, p. 6653 - 6656 (2007/10/02)
The asymmetric syntheses of both enantiomers of 4-hydroxy-2-cyclohexenone and their O-acyl and O-benzyl derivatives are reported.DIBAL and ZnCl2/DIBAL stereoselective reductions of the ketosulfoxides resulting in the sulfinylation of 1,4-cyclohexanedione