1326774-97-3

Upstream product

• 888481-18-3 (3S)-3-(tert-butyl-dimethyl-silanyloxy)-3,7-dimethyl-oct-6-enal 
• 888481-17-2 (3S)-3-((tert-butyldimethylsilanyl)oxy)-3,7-dimethyloct-6-en-1-ol 
• 1326775-04-5 (2-((2'-bromo-4'-(((2''-(trimethylsilyl)ethoxy)methoxy)methyl)phenoxy)methoxy)ethyl)trimethylsilane 
• 1326774-95-1 (3S)-3-((tert-butyldimethylsilyl)oxy)-3,7-dimethyl-1-[2'-((2''-(trimethylsilyl)ethoxy)methoxy)-5'-(((2''-(trimethylsilyl)ethoxy)methoxy)methyl)phenyl]oct-6-en-1-ol 
• 1326774-96-2 (3S)-1-(2'-hydroxy-5'-(hydroxymethyl)phenyl)-3,7-dimethyloct-6-ene-1,3-diol 
• 1326774-94-0 (6S)-6,8-bis-(tert-butyldimethylsilanyloxy)-2,6-dimethyl-oct-2-ene 
• 82188-73-6 (2S,3S)-2,3-epoxygeraniol 
• 106-24-1 Geraniol 
• 29415-97-2 methyl 3-bromo-4-hydroxybenzoate 
• 29922-56-3 2-bromo-4-(hydroxymethyl)phenol 
• 123748-58-3 (3S)-3,7-dimethyl-oct-6-ene-1,3-diol 
• 99-76-3 methyl 4-hydroxylbenzoate 
• 1601390-01-5 (R)-3-(3,7-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)oct-6-enoyl)-4-hydroxybenzaldehyde 

Downstream Products

• 809281-21-8 (3'S)-4-hydroxy-3-(3'-hydroxy-3',7'-dimethyloct-6'-enoyl)benzoic acid 

Relevant academic research and scientific papers

Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to α,β-Unsaturated Carbonyl Compounds

Broadly applicable enantioselective C-B and C-Si bond-forming processes catalyzed by an N-heterocyclic carbene (NHC) were recently introduced; these boryl and silyl conjugate addition reactions (BCA and SCA, respectively), which proceed without the need f

Enantioselective synthesis of boron-substituted quaternary carbon stereogenic centers through NHC-catalyzed conjugate additions of (pinacolato)boron units to enones

The first examples of Lewis base catalyzed enantioselective boryl conjugate additions (BCAs) that generate products containing boron-substituted quaternary carbon stereogenic centers are disclosed. Reactions are performed in the presence of 1.0-5.0 mol %

Enantioselective total synthesis and absolute configuration of the alleged structure of crassinervic acid

An enantioselective synthesis of the structure reported for the natural antifungal compound, (-)-crassinervic acid (1), has been achieved starting from geraniol and p-hydroxybenzoic acid. The key chirality-inducing step is a Sharpless asymmetric epoxidation of an allylic alcohol, on the basis of which the S configuration can be assigned to the (-) natural enantiomer. The discrepancies between the spectroscopic data for synthetic and natural crassinervic acid cast some doubts on the structure assigned to the natural compound. A possible revised structure is discussed.