132698-61-4

Basic information

• Product Name: tris(3,5-difluorophenyl)phosphine
• Synonyms: tris(3,5-difluorophenyl)phosphine
• CAS NO: 132698-61-4
• Molecular Weight: 370.234
• Mol File: 132698-61-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tris(3,5-difluorophenyl)phosphine(CAS DataBase Reference)
• NIST Chemistry Reference: tris(3,5-difluorophenyl)phosphine(132698-61-4)
• EPA Substance Registry System: tris(3,5-difluorophenyl)phosphine(132698-61-4)

Safety Data

• Hazardous Substances Data: 132698-61-4(Hazardous Substances Data)

Upstream product

• 1435-43-4 1-chloro-3,5-difluorobenzene 

Downstream Products

• 1312366-28-1 C₁₄H₁₁F₄OP 
• 206761-32-2 ClAu(P(C₆H₃F₂-m,m)3) 

Relevant articles and documents

Photochemical transformation of chlorobenzenes and white phosphorus into arylphosphines and phosphonium salts

Chlorobenzenes are important starting materials for the preparation of commercially valuable triarylphosphines and tetraarylphosphonium salts, but their use for the direct arylation of elemental phosphorus has been elusive. Here we describe a simple photochemical route toward such products. UV-LED irradiation (365 nm) of chlorobenzenes, white phosphorus (P4) and the organic superphotoreductant tetrakis(dimethylamino)ethylene (TDAE) affords the desired arylphosphorus compounds in a single reaction step.