132717-37-4Relevant articles and documents
One-step preparation of novel conjugated porous polymer with tubular structure
Zhuang, Xiaodong,Zhang, Yi,Cao, Chengan,Zhang, Fan,Wu, Dongqing,Feng, Xinliang
, p. 1112 - 1118 (2013)
A shape-persistent dendritic molecule, tris(4-(2,7-dibromo-9-phenyl-9- fluoren-9-yl)phenyl)amine (TF-6Br), has been readily synthesized in high yield through a concise Friedel-Crafts reaction from triphenylamine and 2,7-dibromo(9-phenyl-fluoren-9-ol). It
H-Shape cyanation opto-electric transmission type material and preparation method and application thereof
-
Paragraph 0075-0077, (2019/06/05)
The invention discloses an H-Shape cyanidation opto-electric transmission type material and a preparation method and application thereof. Double-spiro fluorenyl is connected with a core (Ar1) by spcarbon, an ''H'' structure is exhibited in space, and t
Bigger and Brighter Fluorenes: Facile π-Expansion, Brilliant Emission and Sensing of Nitroaromatics
Ramakrishna, Jagarapu,Venkatakrishnan, Parthasarathy
supporting information, p. 181 - 189 (2017/02/05)
π-Expanded butterfly-like 2D fluorenes and 3D spirobifluorenes 1–5 were synthesized via a DDQ-mediated oxidative cyclization strategy with a high regioselectivity. Through structural modification via π-expansion, it was possible to achieve near-ultraviolet absorption, bright-blue emission, very high near-unity fluorescence quantum yields in solution as well as in film states, and deep-lying HOMO energy levels with excellent thermal stabilities. Furthermore, these electron-rich compounds displayed a notable behavior towards sensing of nitroaromatic explosives, such as picric acid, up to a detection limit of 0.2 ppb.