132783-13-2

Upstream product

• 103-71-9 phenyl isocyanate 
• 925669-95-0 2,3-cis-epoxybutane 
• 88341-32-6 (4R,5R)-2,2-dibutyl-4,5-dimethyl-1,3,2-dioxastannolane 
• 103-72-0 phenyl isothiocyanate 
• 5271-63-6 (4R,5R)-2,2-di-n-butyl-4,5-dimethyl-1,3,2-dioxastannolane 
• 21490-63-1 2,3-trans-epoxybutane 
• 3590-63-4 (4R,5R)-2,2-Dibutyl-4,5-dimethyl-[1,3,2]dioxastannolane 

Downstream Products

• 133192-32-2 trans-7,8-dimethyl-trans-2,3-tetramethylene-1-phenyl-4,6,9-trioxa-1-azaspiro<4.4>nonane 
• 41594-17-6 trans-4,5-dimethyl-3-phenyl-1,3-oxazolidin-2-one 

Relevant academic research and scientific papers

Activation and Control of the Reaction of the Reaction of Dioxastannolane with Carbon Disulfide and Phenyl Isothiocyanate by the Addition of Bases

1,3-Dioxa-2-stannolanes 1 are readily activated by Lewis bases such as Bu3P and Et3N to give cycloadducts on reaction with carbon disulfide or phenyl isothiocyanate under mild conditions.In particular, bases play a characteristic role in the reaction with

Stereospecific Cycloaddition of Heterocumulenes to Oxiranes Catalyzed by Organotin Halide Complexes

Stereospecific cycloaddition of 2,3-disubstituted oxiranes to heterocumulenes, including carbodiimides, isocyanates and carbon dioxide, is catalytically promoted by dialkyltin diiodide-hexamethylphosphoric triamide (HMPA) system, producing various five-membered heterocycles, where the configuration of the carbons in the oxirane ring is retained.In particular, the addition of isocyanates to oxiranes gave stereospecifically two types of products, dioxolan-2-imines and oxazolidin-2-ones independently, while the rearrangement of the former to the latter product has been already proposed.