132816-25-2Relevant academic research and scientific papers
The Geometry of the Carbanionic Moiety Influences the Non-Induced Diastereoselectivity of the -Wittig Rearrangement of Lithiated Diallyl Ethers
Goeppel, Dirk,Muenster, Ingo,Brueckner, Reinhard
, p. 3687 - 3708 (2007/10/02)
Lithiated diallyl ethers with cis- or trans-configuration of the anionic moiety were generated from the diallyl ethers 10, from the vinylogous O,S-acetals 13, and from the O,S-acetals 14 by treatment with nBuLi (in the case of 10) or with lithium naphthal
A direct synthesis of O,S-acetals from aldehydes
Kusche, Andreas,Hoffmann, Rolf,Muenster, Ingo,Keiner, Petra,Brueckner, Reinhard
, p. 467 - 470 (2007/10/02)
In the presence of catalytic to stoichiometric amounts of trimethylsilyl triflate, 1:1:1 mixtures of silyl ethers, phenyl(trimethylsilyl)sulfide, and aldehydes give O,S-acetals in fair to good yields.
