132819-76-2Relevant articles and documents
Mechanistic Insights into the Post-Cyclization Isomerization in Gold-Catalyzed 7-exo-dig-Hydroarylations
Pfl?sterer, Daniel,Schumacher, S?ren,Rudolph, Matthias,Hashmi, A. Stephen K.
, p. 11585 - 11589 (2015/08/03)
The subsequent double-bond isomerization in the synthesis of dibenzocycloheptenes and their heteroaromatic analogues was investigated. In the case of biphenyls, a basic additive completely prevented an isomerization to the thermodynamic product. With elec