595577-77-8Relevant academic research and scientific papers
Mechanistic Insights into the Post-Cyclization Isomerization in Gold-Catalyzed 7-exo-dig-Hydroarylations
Pfl?sterer, Daniel,Schumacher, S?ren,Rudolph, Matthias,Hashmi, A. Stephen K.
, p. 11585 - 11589 (2015/08/03)
The subsequent double-bond isomerization in the synthesis of dibenzocycloheptenes and their heteroaromatic analogues was investigated. In the case of biphenyls, a basic additive completely prevented an isomerization to the thermodynamic product. With elec
An efficient synthesis of furyl sulfonamides from the reaction of furan with in situ generated N-tosyl imines
Padwa, Albert,Zanka, Atsuhiku,Cassidy, Michael P.,Harris, Joel M.
, p. 4939 - 4944 (2007/10/03)
Treatment of an aldehyde and furan with N-sulfinyl-p-toluenesulfonamide/zinc chloride leads to the formation of furyl sulfonamides via an in situ generated N-tosyl imine intermediate. In one case, a novel 4-tosylamino-5,6-dihydro-4H-3-oxa-benz[e]azulene w
