132867-93-7Relevant academic research and scientific papers
Asymmetric induction studies in the intramolecular Pauson-Khand cyclization of 7-alkoxy-1-hepten-6-ynes
Poch,Valenti,Moyano,Pericas,Castro,DeNicola,Greene
, p. 7505 - 7508 (1990)
Asymmetric induction has been achieved in the intramolecular Pauson-Khand reaction of 7-alkoxy-1-hepten-6-ynes derived from chiral alcohols. The stereochemical outcome of the reaction can be explained by the intermediacy of a cis-cobaltabicyclooctane.
