Tetrahedron Letters p. 7505 - 7508 (1990)
Update date:2022-08-03
Topics:
Poch
Valenti
Moyano
Pericas
Castro
DeNicola
Greene
Asymmetric induction has been achieved in the intramolecular Pauson-Khand reaction of 7-alkoxy-1-hepten-6-ynes derived from chiral alcohols. The stereochemical outcome of the reaction can be explained by the intermediacy of a cis-cobaltabicyclooctane.
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