132882-91-8Relevant academic research and scientific papers
Open-chain remote stereocontrol using allylgermanes
Thomas, Eric J.,Weston, Anna P.
, p. 7253 - 7267 (2017/09/11)
Alk-2-enyl(trialkyl- and -triaryl)germanes are transmetallated by tin(IV) halides at ?78 °C with 15 min being sufficient for the transmetallation to proceed effectively to completion. Alk-2-enyl(trialkyl)germanes are transmetallated by both tin(IV) chlori
Remote stereocontrol in reactions between 4- and 5-alkoxyalk-2- enylstannanes and 1-alkoxycarbonylimines and analogues: Stereoselective approaches to novel α-amino acids
Hallett, David J.,Tanikkul, Nongluk,Thomas, Eric J.
supporting information; experimental part, p. 6130 - 6158 (2012/09/05)
Reactions of the allyltin trichloride 45 generated from (4S)-4-benzyloxypent-2-enyl(tributyl)stannane 1 with imines prepared from glyoxylates proceed with useful levels of 1,5-stereocontrol in favour of (4E)-2,6-anti-2-(alkylamino)-6-benzyloxyhept-4-enoat
