132894-45-2Relevant academic research and scientific papers
Characterization and utility of N-unsubstituted imines synthesized from alkyl azides by ruthenium catalysis
Lee, Jin Hee,Gupta, Sreya,Jeong, Wook,Rhee, Young Ho,Park, Jaiwook
supporting information, p. 10851 - 10855 (2013/01/15)
Shine a light: A fluorescent light-induced synthetic method for the title compounds has been developed and the chemoselective nature of the reaction is highlighted by the observation of the cis/trans isomers of various N-unsubstituted imines. The synthetic utility of this method is demonstrated by the one-pot imine formation/asymmetric allylation sequence of benzyl azide catalyzed by 1. (Ipc=isopinocampheyl). Copyright
The reactivity of polyfunctionalized iminophosphoranes
Carite,Alazard,Ogino,Thal
, p. 7011 - 7014 (2007/10/02)
The reactivity of some functionalized azides has been studied under the conditions of the Staudinger and aza-Wittig reactions. With the azides having a trifluoroacetamido group in the ortho-position of the aromatic ring, intramolecular reactions have been observed which allow new synthetic approaches to indoline and imidazoindole compounds.
