132927-34-5Relevant academic research and scientific papers
A novel strategy for regio- and stereocontrol in [4 + 2] cycloadditions. Intramolecular Diels-Alder reaction of a sllyl acetal triene
Craig, Donald,Reader, John C.
, p. 6585 - 6588 (1990)
The synthesis of the novel silyl acetal-containing triene 1 is described. Triene 1 underwent regiospecific and highly stereo selective intramolecular Diels-Alder reaction to give bicycle 5. Acidic methanolysis of 5 gave hydroxylactone 2, whose structure was established by X-ray crystallography.
Intramolecular Diels-Alder Reactions of Silyl Acetal-tethered Trienes
Ainsworth, Peter J.,Craig, Donald,Reader, John C.,Slawin, Alexandra M. Z.,White, Andrew J. P.,Williams, Dawid J.
, p. 11601 - 11622 (2007/10/02)
The synthesis and intramolecular Diels-Alder reactions of a series of silyl acetal-tethered trienes 4-9 are described.The cycloadditions show complete regioselectivity, and in all but one case give exclusively cis-fused bicyclic products.The selectivities
