A novel strategy for regio- and stereocontrol in [4 + 2] cycloadditions. Intramolecular Diels-Alder reaction of a sllyl acetal triene

DOI: 10.1016/S0040-4039(00)97123-5

Source and publish data:

Tetrahedron Letters p. 6585 - 6588 (1990)

Update date:2022-09-26

Topics:

Authors:

Craig, Donald

Reader, John C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)97123-5

The synthesis of the novel silyl acetal-containing triene 1 is described. Triene 1 underwent regiospecific and highly stereo selective intramolecular Diels-Alder reaction to give bicycle 5. Acidic methanolysis of 5 gave hydroxylactone 2, whose structure was established by X-ray crystallography.

Full text of DOI:10.1016/S0040-4039(00)97123-5

Products guided by the article

Product name:<1R*,7R*,10S*,11R*>-11-methoxycarbonyl-10-methyl-4,4-diphenyl-3,5,4-dioxasilabicyclo<5.4.0>-8-undecene

Cas No:132927-34-5

R&D Labs maybe for 132927-34-5

ShenZhen InnoSyn Biotech Co.,Ltd

website:http://www.innosyns.com

Contact:+86-755-28351685

Address:Floor 5 & 6, Building A1, HAIKEXING Strategic Innovative Industrial Park, 16 BaoShan Road, PingShan District
Lanling Hongchuang Flame Retardant Co., Ltd.

Contact:+86-531-68858132

Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)
TIANJIN ZHONGXIN CHEMTECH CO.,LTD.

Contact:86-022-66880623

Address:FINANCIAL STREET WEST BLK 7, #308, NO.52 XINCHENG WEST ROAD, TEDA, TIANJIN, P.R.CHINA
Taiwan Surfactant Corp.

Contact:886 2 2541 0022

Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.
KINHENG CHEMICAL(SHANGHAI)CO., LTD.

Contact:+8621-60490170

Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.

Relevant to this article

Synthesis of Methyl- and Methoxy-Substituted β-D-Ribofuranosylnaphthalene Derivatives by Lewis Acid Catalyzed Ribofuranosylation

Doi:10.1021/jo00011a059
(1991)
DDQ-promoted dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones by a radical ion mechanism

Doi:10.1039/c1cc11633a
(2011)
Design, synthesis and evaluation of nitric oxide releasing derivatives of 3-n-butylphthalide as antiplatelet and antithrombotic agents

Doi:10.1039/c1ob05478c
(2011)
Synthetic Studies of Diels-Alder Adduct of Furan. Formal Total Synthesis of (+/-)-Avenaciolide

Doi:10.1246/bcsj.59.3881
(1986)
ACIDE 2-FLUORO-2-PHENYLACETIQUE. PARTIE 3. CORRELATION ENTRE LA CONFIGURATION DE SES AMIDES D'AMINES CHIRALES ET LES DEPLACEMENTS CHIMIQUES DU PROTON ET DU FLUOR

Doi:10.1016/S0022-1139(00)84998-2
(1990)
Structure-activity relationships in tripodal transmembrane anion transporters: The effect of fluorination

Doi:10.1021/ja205884y
(2011)

Article Doi