A novel strategy for regio- and stereocontrol in [4 + 2] cycloadditions. Intramolecular Diels-Alder reaction of a sllyl acetal triene

DOI: 10.1016/S0040-4039(00)97123-5

Source and publish data:

Tetrahedron Letters p. 6585 - 6588 (1990)

Update date:2022-09-26

Topics:

Authors:

Craig, Donald

Reader, John C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)97123-5

The synthesis of the novel silyl acetal-containing triene 1 is described. Triene 1 underwent regiospecific and highly stereo selective intramolecular Diels-Alder reaction to give bicycle 5. Acidic methanolysis of 5 gave hydroxylactone 2, whose structure was established by X-ray crystallography.

Full text of DOI:10.1016/S0040-4039(00)97123-5

Products guided by the article

Product name:<1R*,7R*,10S*,11R*>-11-methoxycarbonyl-10-methyl-4,4-diphenyl-3,5,4-dioxasilabicyclo<5.4.0>-8-undecene

Cas No:132927-34-5

R&D Labs maybe for 132927-34-5

SHENYANG COMEBOARD TECHNOLOGY CO., LTD

Contact:+86-24-25724626

Address:Room2210,Tianbao International Building,No.8-1 Weigong South Street,Tiexi District,Shenyang,China
Shanghai Hongbang Medical Technology CO.,. Ltd

Contact:13671516988 /18917636693

Address:Room1, No67 Building, Yongde Road369, Wujing Town, Minhang Districy, Shanghai CIty, China.
Yangling Ciyuan biotech Co., Ltd.

Contact:86-15802970736

Address:2-1804, International Park Mansion, No.2, South Fengdeng Road, Lianhu District
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.

Contact:+86-186-02659358

Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China
ZK Biochem Group Co., Ltd

Contact:+86-532-80762375

Address:No. 6, Hongkong Middle Road, Qingdao, China

Relevant to this article

Synthesis of Methyl- and Methoxy-Substituted β-D-Ribofuranosylnaphthalene Derivatives by Lewis Acid Catalyzed Ribofuranosylation

Doi:10.1021/jo00011a059
(1991)
DDQ-promoted dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones by a radical ion mechanism

Doi:10.1039/c1cc11633a
(2011)
Design, synthesis and evaluation of nitric oxide releasing derivatives of 3-n-butylphthalide as antiplatelet and antithrombotic agents

Doi:10.1039/c1ob05478c
(2011)
Synthetic Studies of Diels-Alder Adduct of Furan. Formal Total Synthesis of (+/-)-Avenaciolide

Doi:10.1246/bcsj.59.3881
(1986)
ACIDE 2-FLUORO-2-PHENYLACETIQUE. PARTIE 3. CORRELATION ENTRE LA CONFIGURATION DE SES AMIDES D'AMINES CHIRALES ET LES DEPLACEMENTS CHIMIQUES DU PROTON ET DU FLUOR

Doi:10.1016/S0022-1139(00)84998-2
(1990)
Structure-activity relationships in tripodal transmembrane anion transporters: The effect of fluorination

Doi:10.1021/ja205884y
(2011)

Article Doi