Tetrahedron Letters p. 6585 - 6588 (1990)
Update date:2022-09-26
Topics:
Craig, Donald
Reader, John C.
The synthesis of the novel silyl acetal-containing triene 1 is described. Triene 1 underwent regiospecific and highly stereo selective intramolecular Diels-Alder reaction to give bicycle 5. Acidic methanolysis of 5 gave hydroxylactone 2, whose structure was established by X-ray crystallography.
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