132927-36-7Relevant academic research and scientific papers
A novel strategy for regio- and stereocontrol in [4 + 2] cycloadditions. Intramolecular Diels-Alder reaction of a sllyl acetal triene
Craig, Donald,Reader, John C.
, p. 6585 - 6588 (2007/10/02)
The synthesis of the novel silyl acetal-containing triene 1 is described. Triene 1 underwent regiospecific and highly stereo selective intramolecular Diels-Alder reaction to give bicycle 5. Acidic methanolysis of 5 gave hydroxylactone 2, whose structure was established by X-ray crystallography.
