132928-39-3

Basic information

• Product Name: 2-Propenoic acid, 3-phenyl-, 2,3-dihydroxypropyl ester, (2E)-
• Synonyms: 2-Propenoic acid, 3-phenyl-, 2,3-dihydroxypropyl ester, (2E)-
• CAS NO: 132928-39-3
• Molecular Formula: C₁₂H₁₄O₄
• Molecular Weight: 222.23716
• Mol File: 132928-39-3.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Propenoic acid, 3-phenyl-, 2,3-dihydroxypropyl ester, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-phenyl-, 2,3-dihydroxypropyl ester, (2E)-(132928-39-3)
• EPA Substance Registry System: 2-Propenoic acid, 3-phenyl-, 2,3-dihydroxypropyl ester, (2E)-(132928-39-3)

Safety Data

• Hazardous Substances Data: 132928-39-3(Hazardous Substances Data)

Upstream product

• 140-10-3 (E)-3-phenylacrylic acid 
• 56-81-5 glycerol 
• 4192-77-2 ethyl cinnamate 
• 104-55-2 3-phenyl-propenal 
• 621-82-9 Cinnamic acid 
• 132928-38-2 (2,2-dimethyl-1,3-dioxolane-4-yl)methyl cinnamate 
• 109573-58-2 trans-cinnamic acid-(3-chloro-2-hydroxy-propyl ester) 

Relevant articles and documents

Organocatalytic valorisation of glycerol: Via a dual NHC-catalysed telescoped reaction

A general telescoped reaction for the NHC-catalysed carbonation and aerobic esterification of glycerol and 2-amino-2-methylpropane-1,3-diol has been developed. The reaction provides highly functionalised glycerol derivatives in good to excellent yields (up to 95%) using low catalyst loadings and ambient conditions.

Synthesis of Some Phenylpropanoid Monoglycerides via the Mitsunobu Protocol

Natural monoglycerides of cinnamic, ferulic and p-coumaric acids were synthesized in good to high overall yields from isopropylidene glycerol via the Mitsunobu reaction and further deprotection of the corresponding acetonides with Amberlyst 15. The method avoids the need of protection of the phenolic hydroxyls. During the Mitsunobu esterifications a strong influence of the acid strength on the efficacy and outcome of the reaction was observed.