132929-34-1

Basic information

• Product Name: Benzoic acid (1R,2S,4R)-1-(7-oxa-bicyclo[2.2.1]hept-5-en-2-yl)methyl ester
• CAS NO: 132929-34-1
• Molecular Weight: 230.263
• Mol File: 132929-34-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzoic acid (1R,2S,4R)-1-(7-oxa-bicyclo[2.2.1]hept-5-en-2-yl)methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (1R,2S,4R)-1-(7-oxa-bicyclo[2.2.1]hept-5-en-2-yl)methyl ester(132929-34-1)
• EPA Substance Registry System: Benzoic acid (1R,2S,4R)-1-(7-oxa-bicyclo[2.2.1]hept-5-en-2-yl)methyl ester(132929-34-1)

Safety Data

• Hazardous Substances Data: 132929-34-1(Hazardous Substances Data)

Upstream product

• 24363-23-3 (+/-)-7-oxabicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid 
• 98-88-4 benzoyl chloride 
• 89898-05-5 7-oxabicyclo<2.2.1>hept-5-en-2-exo-ylmethanol 
• 89898-05-5 (1RS,2SR,4RS)-7-oxabicyclo[2.2.1]hept-5-ene-2-methanol 
• 24363-23-3 (+/-)-7-oxabicyclo[2.2.1]hept-5-ene-2-endo-carboxylic acid 

Downstream Products

• 132929-45-4 2-endo-((Benzyloxy)methyl)-5-endo-chloro-6-exo-(phenylsulfenyl)-7-oxabicyclo<2.2.1>heptane 
• 132929-43-2 2-endo-benzoyloxymethyl-5-endo-bromo-6-exo-phenylselenyl-7-oxabicyclo<2.2.1>heptane 

Relevant articles and documents

Synthesis of novel carbocyclic nucleoside analogues derived from 7-oxabicyclo[2.2.1]heptane-2-methanol

Hydroboration of [(lR*,2R*,4R*)-7-oxabicyclo[2.2.1]hept- 5-en-2-yl]methyl benzoate (5), which was prepared by Diels-Alder reaction of furan with acrolein and subsequent reduction and benzoylation of the Diels-Alder product, afforded [(lR*,2S*,4S*,6S*)-6-h

Regioselective electrophilic additions to 2-alkoxy- and 2-alkoxymethyl-7-oxabicyclo[2.2.1]hept-5-ene derivatives

The influence of the stereochemistry at C-2 on the selectivity of the reaction between PhSeBr and 2-alkoxymethyl substituted oxanorbornenes has been studied. All endo isomers displayed complete regio- and stereocontrol with incorporation of the electrophi