13294-86-5

Upstream product

• 120-12-7 anthracene 
• 292638-85-8 acrylic acid methyl ester 
• 75-66-1 2-methylpropan-2-thiol 
• 119564-99-7 (S)-(+)-2-bromodibenzobicyclo<2.2.2>octadiene-2-carboxylate 
• 18910-47-9 9,10-dihydro-9,10-ethenoanthracene-12-carboxylic acid methyl ester 

Downstream Products

• 6624-25-5 (9,10-dihydro-9,10-ethano-anthracen-11-yl)-methanol 
• 120-12-7 anthracene 
• 292638-85-8 acrylic acid methyl ester 
• 79655-58-6 C₃₂H₂₄O 
• 79655-60-0 C₂₇H₂₂O₂ 
• 79655-57-5 C₂₇H₂₂O 
• 79655-59-7 C₂₆H₂₀O 
• 121597-39-5 (+/-)-9',10'-dihydro-cis-2-cyano-3,3-diphenylspiro-5-one 
• 121597-37-3 (+/-)-9',10'-dihydro-trans-2-cyano-cis-3-phenylspiro-5-one 
• 121597-37-3 (+/-)-9',10'-dihydro-cis-2-cyano-cis-3-phenylspiro-5-one 

Relevant academic research and scientific papers

RESIST COMPOSITION AND METHOD OF FORMING RESIST PATTERN

A resist composition including a compound represented by formula (bd1), a total amount of the acid-generator component and the basic component being 20 to 70 parts by weight, relative to 100 parts by weight of the base material component (wherein Rx1 to Rx4 represents a hydrogen atom or a hydrocarbon group, or two or more of Rx1 to Rx4 may be mutually bonded to form a ring structure; Ry1 and Ry2 represents a hydrogen atom or a hydrocarbon group, or Ry1 and Ry2 may be mutually bonded to form a ring structure; Rz1 to Rz4 represents a hydrogen atom or a hydrocarbon group, or two or more of Rz1 to Rz4 may be mutually bonded to form a ring structure; provided that at least one of Rx1 to Rx4 , Ry1 , Ry2 and Rz1 to Rz4 has an anionic group; and Mm+ represents an m-valent organic cation).

RESIST COMPOSITION, METHOD OF FORMING RESIST PATTERN, COMPOUND, AND ACID GENERATOR

A resist composition containing a compound represented by the general formula (bd1-1), (bd1-2) or (bd1-3); in the formula, Rx1 to Rx4 represent a hydrocarbon group or a hydrogen atom or may be mutually bonded to form a ring structure; Ry1 to Ry2 represent a hydrocarbon group or a hydrogen atom or may be mutually bonded to form a ring structure, Rz1 to Rz4 represent a hydrocarbon group or a hydrogen atom or may be mutually bonded to form a ring structure. At least one of Rx1 to Rx4, Ry1 to Ry2 and Rz1 to Rz4 has an anion group, M1m+ represents a sulfonium cation having a sulfonyl group, R001 to R003 each independently represent a monovalent organic group; provided that at least one of R001 to R003 is an organic group having an acid dissociable group; and M3m+ represents an m-valent organic cation having an electron-withdrawing group.

RESIST COMPOSITION, METHOD OF FORMING RESIST PATTERN, COMPOUND, AND ACID GENERATOR

A resist composition including a base component which exhibits changed solubility in a developing solution under action of acid, and a compound (B1) having an anion moiety and a cation moiety and being represented by general formula (b1) (wherein R01 to R014 each independently represents a hydrogen atom or a hydrocarbon group which may have a substituent, or two or more of R01 to R014 may be mutually bonded to form a ring structure, provided that at least two of R01 to R014 are mutually bonded to form a ring structure, and at least one of R01 to R014 has an anion group, and the anion moiety as a whole forms an anion having a valency of n; n represents an integer of 1 or more; represents an integer of 1 or more; and Mm+ represents an organic cation having a valency of m).

Rhodium(I)-catalyzed intramolecular ene reaction of vinylidenecyclopropanes and alkenes for the formation of bicyclo[5.1.0]octylenes

"Chemical Equation Presented" An efficient catalytic system for the intramolecular ene reaction of allene and alkene of diarylvinylidenecyclopropanes has been established. The reaction was achieved by using [RhCl(CO)2]2 as the cataly

Facile microwave-assisted synthesis of 9,10-dihydro-9,10-ethanoanthracene- 11-carboxylic acid methyl ester

A facile, high yielding synthesis of 9,10-dihydro-9,10-ethano- anthracene-11-carboxylic acid methyl ester using a modified commercial domestic microwave oven is reported.

Deuterium isotope effects and product studies for the oxidation of N(ω)-allyl-L-arginine and N(ω)-allyl-N(ω)-hydroxy-L-arginine by neuronal nitric oxide synthase

The nitric oxide synthases (NOS), which require heme, tetrahydrobiopterin, FMN, FAD, and NADPH, catalyze the O2-dependent conversion of L-arginine to L-citrulline and nitric oxide. N(ω)-Allyl-L-arginine, a mechanism-based inactivator of neuronal NOS, also is a substrate, producing L-arginine, acrolein, and H2O (Zhang, H. Q.; Dixon, R. P.; Marletta, M. A.; Nikolic, D.; Van Breemen, R.; Silverman, R. B. J. Am. Chem. Soc. 1997, 119, 10888). Two possible mechanisms for this turnover are proposed, one initiated by allyl C-H bond cleavage and the other by guanidino N-H cleavage, and these mechanisms are investigated with the use of N(ω)-allyl-L-arginine (1), N(ω)-[1,1-2H2]allyl-L-arginine (7), N(ω)-allyl-N(ω)-hydroxy-L-arginine (2) and N(ω)-[1,1-2H2]allyl-N(ω)-hydroxy-L-arginine (8) as substrates. Significant isotope effects on the two kinetic parameters, k(cat) and k(cat)/K(m), are observed in case of 1 and 7 during turnover, but not with 2 and 8. No kinetic isotope effects are observed for either compound in their role as inactivators. These results support a mechanism involving initial C-H bond cleavage of N(ω)-allyl-L-arginine followed by hydroxylation and breakdown to products. Copyright (C) 2000.

Mechanistic aspects of the reaction of anionic iron(0)-olefin complexes with organic halides. detection and characterization of paramagnetic organometallic intermediates

The scope and the mechanism of the reactions of [CpFe(COD)][Li(TMEDA) (Cp = C5H5-; COD = 1,5-cyclooctadiene; TMEDA = Me2NCH2CH2NMe2), 1, with a number of organic monohalides and geminal dih

Reductive decarboxylation of N-(acyloxy)phthalimides via redox-initiated radical chain mechanism

Highly efficient reductive decarboxylation of N-(acyloxy)phthalimides which are readily prepared from carboxylic acids was achieved by visible light irradiation using Ru(bpy)3Cl2 as a sensitizer in the presence of BNAH and t-BuSH via radical chain mechanism.

Synthesis of δ-L-α-aminoadipoyl-L-cysteinyl- D-allylglycine, and eight deuterated analogues, substrates for the investigation of the mechanism of action of isopenicillin n synthase

The synthesis of δ-L-α-aminoadipoyl-L-cysteinyl-D-allylglycine (1a) from its component amino acids is described, along with the synthesis of eight analogues (1b-i) specifically deuterated at C-3 and/or C-5 of the allyglycine residue.