1330147-04-0Relevant articles and documents
Rh-Catalyzed domino synthesis of 4-hydroxy-3-methylcoumarins via branch-selective hydroacylation
Rao, Maddali L.N.,Ramakrishna, Boddu S.,Nand, Sachchida
, p. 9275 - 9279 (2019/11/13)
A Rh-catalyzed domino synthesis of 4-hydroxy-3-methylcoumarins via branch-selective hydroacylation of acrylates and acrylamides using salicylaldehydes is described. This protocol under phosphine-free Rh-catalyzed conditions provided 4-hydroxy-3-methylcoum
Mechanistic investigation of the enantioselective intramolecular stetter reaction: Proton transfer is the first irreversible step
Moore, Jennifer L.,Silvestri, Anthony P.,De Alaniz, Javier Read,Dirocco, Daniel A.,Rovis, Tomislav
, p. 1742 - 1745 (2011/06/17)
A study on the mechanism of the asymmetric intramolecular Stetter reaction is reported. This investigation includes the determination of the rate law, kinetic isotope effects, and competition experiments. The reaction was found to be first order in aldehy